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gen chem
thermochemistry
Question | Answer |
---|---|
______ determines wheter a rxn would be spontaneous | thermodynamics |
_____ no exchange with surrounding | isolated sytem |
______ can exchange energy but no matter | closed system |
_____ exchange both energy and matter | open system |
_____ no exchange of heat | adiabatic |
eNdothermic | gaiNs heat (+) |
in const vol calorimeter the system is | adiabatic: no gain/loss of heat |
gen formula for enthalpy | Hrxn= Hprod- Hreact |
+H corresponds to | Endothermic process non spontaneous |
formula for enthalpy of rxn | sumHprod- sumHreactant |
bond breakage is always | endothermic ( uses energy ) - |
bond formation is always | exothermic (+) energy released |
formula for enthalpy with bond dissociation energy | H broken bonds + H bonds formed (energy in - energy released) |
bond disociation energy | energy required to break bond |
_____ measure of disorder | entropy |
formula for change entropy | S (fin)- S (initial) |
unit for entropy | energy/temp (J/K) |
_____ max energy released in a process | Gbbs free energy |
formula for Gibbs free energy | G=H-TS |
G is negative then its | spontaneous |
G is positive then its | nonspontaneous |
G =0 then its | at equilibrium |
rate of rxn is dependent on | activation energy NOT G |
bond dissociation problems | bonds broken -bonds formed the ones with subscript numbers are the ones that became broken 2h-->H2 bond break |
work done on surroundin | - (negative) |
system loses heat q= | negatve |
net enthalpy problems when they give heat of formation | Hprod-Hreactants |