Save
Busy. Please wait.
Log in with Clever
or
show password
Forgot Password?
Don't have an account?  Sign up 
Sign up using Clever
or
Username is available taken
show password


Make sure to remember your password. If you forget it there is no way for StudyStack to send you a reset link. You would need to create a new account. Your email address is only used to allow you to reset your password. See our Privacy Policy and Terms of Service.

Already a StudyStack user? Log In

Reset Password
Enter the associated with your account, and we'll email you a link to reset your password.
focusNode
Didn't know it?
click below
 
Knew it?
click below
Don't Know
Remaining cards (0)
Know
0:00
edit
Embed Code - If you would like this activity on your web page, copy the script below and paste it into your web page.

  Normal Size     Small Size show me how

Dat organic

Aldehyde + ketone

QuestionAnswer
aldehyde gen formula R-C=O \H
ketone gen formula R-C=O \R
in aldehyde the C=O occupies C-1
cycloalkane+ aldehyde cycloalkanecarbaldehyde
in ketone if C=O is substituent attached to carboxylic acid "oxo" prefix
Synthesis of aldehyde using alcohol "oxidation" primary alcohol with PCC/ na dicromate
synthesis of ketone using alcohol sec alcohol with PcC/na dicromate
synthesis of aldehydes/ketone using alkene ozone + alkene
keto form C=O
enol form C-OH
C=O is polar therefore liable for nucleophilic attack
water + aldehyde or ketones H added to O and OH added to C R-C-OH OH/\R
alcohol + aldehyde or ketone H added to O and RO added to C R-C-OH RO/\R (hemicetal(H) or hemiketal (R)
acetal 2OH added to aldehyde R-C-OR OR/\H
ketal 2 OH added to ketone R-C-OR OR/\R
HCN + aldehyde/ ketone H adds to O and CN to C R-C-OH CN/\R
ammonia + aldehyde/ ketone forms imine R-C=NH \R
aldol has both aldehyde and alcohol H-C=O \C-R-OH
aldol + heat loses OH and H from R to form double bond H-C=O \C=R
wittig rxn convert aldehydes and ketones to alkenes (C=O to C=C) ylide/ phosphorane + aldehyde or ketone
ketones can be reduced to alcohols
aldehydes can be oxidized to ____ and reduced to ____ carboxylic acids; alcohol
aldehyde + KmnO4 CrO3 Ag2O or H2O2 carboxylic acid
ketone + LAh or NaBh4 alcohol
wolf kishner aldehyde or ketone completely reduced to alkane H2NNH2 in base
clemmensen aldehyde or ketone reduced to alkane HgZn in HCL (acid)
iodoform tests methyl ketones
Created by: smuttz
Popular DAT sets

 

 



Voices

Use these flashcards to help memorize information. Look at the large card and try to recall what is on the other side. Then click the card to flip it. If you knew the answer, click the green Know box. Otherwise, click the red Don't know box.

When you've placed seven or more cards in the Don't know box, click "retry" to try those cards again.

If you've accidentally put the card in the wrong box, just click on the card to take it out of the box.

You can also use your keyboard to move the cards as follows:

If you are logged in to your account, this website will remember which cards you know and don't know so that they are in the same box the next time you log in.

When you need a break, try one of the other activities listed below the flashcards like Matching, Snowman, or Hungry Bug. Although it may feel like you're playing a game, your brain is still making more connections with the information to help you out.

To see how well you know the information, try the Quiz or Test activity.

Pass complete!
"Know" box contains:
Time elapsed:
Retries:
restart all cards