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Dat organic Test

Enter the letter for the matching Answer
incorrect
1.
strong nucleophile
incorrect
2.
for cycloalkenes that have a branched grp we
incorrect
3.
Alkene + hot basic KMNO4
incorrect
4.
favors highly substituted carbocation, protic solvents, good leaving group and HIGH temps
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5.
X2 addition to alkane results
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6.
in aprotic solvents (DMSO) _______ bases are better nucleophiles
incorrect
7.
alkyne have ____ boiling points than alkenes
incorrect
8.
in Protic solvents _______ atoms are better nucleophiles, increases down a group
incorrect
9.
STRONG BASE, STERIC HINDRANCE,more substituted double bond is preferred,
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10.
Alkene + HX in presence of peroxides, oxygen or other impurities
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11.
Alkene + Ozone with Zn
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12.
Alkyne + X2
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13.
protic solvent have Ha attached to
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14.
Leaving groups are _______ bases
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15.
Alkene+ B2H6
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16.
aprotic solvents favor _____________
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17.
general formula for aromatic compd
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18.
non terminal Alkyne + basic KMNO4 then acid
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19.
alkene stability is based on
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20.
nh2 on benzene
A.
hydroboration; Boron attach to less subst C then H adds to most stable C then B is replaced by OH. Syn addition and anti markov
B.
adds =O splits the original double bond and adds H, 1 product
C.
aniline
D.
2 carboxylc acids
E.
markovnikov, alken halide
F.
the number of substitution about the double bond more is more stable
G.
strong bases the halides F is strongest
H.
larger atoms,( I is stronger than F)
I.
weak; I is preferred over F
J.
electroneg atoms like O, N, F
K.
ability to fit so cant be bulky
L.
E1
M.
4n+2pi electron
N.
1. terminal alkene= carboxylic acid +Co2 2. non terminal = 2 Carboxylic acids
O.
Free radical substitution BR attach to more substituted C Cl looks for primary C
P.
assign1 at the start of alkene then move thru the alkene then number the branch grp
Q.
E2
R.
higher
S.
free radical rxns which are antimarkovnikov ( X adds first and H last to more subst C)
T.
SN2 or E2 because they have strong bases that would react with a proton if present
Type the Answer that corresponds to the displayed Question.
incorrect
21.
arom compds + X2 in lewis acid eg FeBr3
incorrect
22.
1,2 disub in aryl compds
incorrect
23.
bulky nucleophile is a _______ nucleopjile and ______ base and favors _____ rxns
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24.
cis/z have higher ______ than trans/ E
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25.
_______ Oh on benzene
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26.
arom compd + So3 in H2SO4
Type the Question that corresponds to the displayed Answer.
incorrect
27.
Sn2: the halides are added anti (opp)to each other
incorrect
28.
(H2+ Pd)----> cis alkene
incorrect
29.
lose H and OH forms alkene
incorrect
30.
syn, alkene ( adds 2 H)

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Created by: smuttz
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