Cho 8 Aldehydes and ketones
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| charges in carbonyl | carbon is partially positive, oxygen is partially negative
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| aldehydes are ---- functional groups and ketones are ----- | aldehydes are terminal, ketones are midchain
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| how can aldehydes be synthesized from primary alcohols | with PCC
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| what can aldehydes be oxidized or reduced too | oxidized to carboxylic acids, reduced too secondary alcohols
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| what can ketones be oxidized or reduced too | cannot be oxidized further, can be reduced to secondary alcohols
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| what is significant about the enol form | it can act as a nucleophile, but it is not prevalent in solution
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| where will nucleophiles typically add to the carbonyl carbon | to the electropositive carbonyl carbon
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| Wittig reaction | swaps out C=O for C=C
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| Wolf-Kishner and Clemmensen | The Wold-Kischner reduction and Clemmensen reduction reduce ketones or aldehydes to alcohols
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