DAT Kaplan OChem
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| alkanes are the simplest organic molecules consisting of only ___ and ___ atoms held together by single bonds | show 🗑
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| in IUPAC, common should be placed between __ | show 🗑
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| show | words
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| show | cyclo
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| alkenes uses the prefix ___- | show 🗑
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| show | double
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| show | double
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| show | monosubsituted
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| allyl derivatives are ____ substituted at the C3 position | show 🗑
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| Methylene refers to the ___ group | show 🗑
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| cycloalkenes are named like cycloalkanes but the suffix ____ rather than ____ | show 🗑
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| show | 1
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| alkynes are compounds that posses carbon carbon ___ bonds | show 🗑
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| common name for ethyne is | show 🗑
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| show | alkyl
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| haloalkane can be named | show 🗑
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| show | diols
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| esthers are named with the prefix | show 🗑
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| show | oxygen
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| show | oxiranes/epoxides
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| show | al
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| show | -one
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| carbocylic acids end with | show 🗑
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| show | amine
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| show | C=OOH
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| Ester | show 🗑
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| show | C=OX
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| Nitrile/Cyandile | show 🗑
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| show | C=O-H
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| show | C=O-C
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| show | same
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| show | opposite
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| the alkene called Z is when the two ___ priority substituents on each carbon lie on the same side of the double bond. | show 🗑
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| higher the atomic number, the higher the ____ | show 🗑
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| show | E
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| show | chiral center, like ur right and left hand putting in a glove. they are the same thing but different.
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| show | superimposed. means they are identical. like AA
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| show | enantiomers
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| show | R
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| show | S
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| horizonta lines come ___ of the page | show 🗑
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| enantiomers has identical chemical and physical properties with one exception of ___ | show 🗑
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| if plane polarized light is passed through an optically active compound, the orientation of the plane is rotated by an angle __- | show 🗑
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| a compound that rotates the pane of the polarized light to the right or clockwise is _____ and indicated (+) | show 🗑
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| show | levoratory
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| Specific rotation [alpha] = EQUATION | show 🗑
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| racemix mixture is a mixture of equal concentrations of both ___ and ___ enantimoers | show 🗑
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| Diastereomers are for any molecules with __ chiral centers | show 🗑
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| Mirror images of each other are called | show 🗑
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| stereoisomers that are not mirror images of each other are caleld | show 🗑
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| Meso compounds are if a plane of symmetry exists which makes the molecule ___ optically active | show 🗑
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| L-tartaric and D-tartaric acids ____ optically active | show 🗑
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| L-tartaric acid is when the ___ is on top of the the __- | show 🗑
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| show | OH; H
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| Conformational isomers are compounds that___ only by rotation about one or more single bonds | show 🗑
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| The most stable conformation is when the two methyl groups (C1 and C4) are oriented ___ degrees from each other | show 🗑
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| 180 degrees confirmation with no overlap of atoms is known as the ___ confirmation | show 🗑
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| show | 60
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| eclipse confirmation in which two methyl groups are ___ apart and overlap with the H atoms | show 🗑
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| When the two methyl groups are overlapping each other its called a ___ | show 🗑
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| show | ideal
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| strain energies: ____ strain results when cyclic molecules must assume conformation that have eclipsed interactions | show 🗑
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| nonbonded strains result when atoms or groups compete for the ___ space | show 🗑
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| show | axial because of the steric repulsion
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| show | chair, boat, twist
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| structural isomers are compounds that share the same ____ | show 🗑
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| show | attached
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| achrial means when the carbon are attached to | show 🗑
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| show | another
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| show | spatial
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| if a lower energy bonding orbital is produced, then the signs of the wave functions are the ___ | show 🗑
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| show | different
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| show | stronger
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| single bond order is a ____ bond | show 🗑
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| single bond order has an angle of ___ and hybridization of ___ | show 🗑
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| show | 1 sigma and 1 pi
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| show | sp2
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| show | 120
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| show | 109.5
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| triple bond order has ___ and ___ bond | show 🗑
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| triple bond order has a hybridization of __- | show 🗑
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| in alkanes, as the molecular weight increases and chain length increases then | show 🗑
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| show | decrease in MP BP and Density
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| show | right
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| show | equal on the right and left
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| termination has two dots on the | show 🗑
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| show | heat
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| show | basicity. stronger the base, stronger the nucleophile.
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| best leaving groups in halogens start from the | show 🗑
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| best nucleophilic strengths are from the | show 🗑
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| show | True
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| show | Higher
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| Nature of leaving group: ___ bases dissociate more easily from alkyl chain and thus make better leaving groups, increasing rate of carbocation formation | show 🗑
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| SN1: the rate is ___ dependent on the concentration or the nature of the nucleophile | show 🗑
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