Metabolism
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Metabolism | The sum of all chemical transformations taking place in a cell. The overall process by which living systems acquire and utilize energy. The overall network of enzyme catalyzed reaction pathways.
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Metabolic Pathways | Linear Pathway: glycolysis
Branched Pathway: amino acid biosynthesis
Cyclic Pathway: citric acid cycle.
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Network Nature of Metabolism | Initial reactants vs. intermediates vs. final products.
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Metabolic Pathways | Linear Pathway: glycolysis
Branched Pathway: amino acid biosynthesis
Cyclic Pathway: citric acid cycle
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Anabolism | build large molecules, require ATP, divergent pathways
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Pharmacy relevance | Must be spontaneous: thermodynamically favorable, negative delta G
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Oxidizing Agent | removes electrons from another reactant in a redox reaction. the oxidizing agent is reduced.
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Redox Reactions | An oxidizing agent (also called an oxidant, oxidizer or oxidiser) can be defined as a substance that removes electrons from another reactant in a redox chemical reaction. The oxidizing agent is reduced. Having electrons taken away.
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delta G prime | standard free energy when all components = 1.0M at pH7, 25C 1 atm.
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delta G | actual free energy change under cellular conditions.
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Free energy changes during chemical reactions | negative delta G: spontaneous
positive delta G: need coupled reactions, Hess' Law
zero delta G: Lechatelier's Principle.
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large Keq | spontaneous, large -deltaG or very negative delta G.
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phosphoryl group transfer details | special role of ATP as the energy currency that links catabolism and anabolism. use ATP to drive: anabolism, mechanical motion, & active transport.
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Reverse Reactions | Same absolute value just change the sign.
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Importance of ATP intermediate phosphoryl transfer potential | It is in the middle and may drive other reactions.
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Regulation of metabolic pathways | catabolic pathways are only activated when it is needed.
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phosphocreatine during exercise | 100m sprint fast-twitch muscle uses phosphocreatine to generate ATP.
marathon- slow-twitch muscle uses slow and steady process of nutrient catabolism/oxidative phosphorylation(mitochondria)
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Fats | Most Energy; fatty acids.
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