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Chapter 14 - Carbohydrates

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Term
Definition
carbohydrates   aldehydes or ketones with many hydroxyl groups  
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monosaccharides   glucose, fructose, galactose, mannose  
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glyceraldehyde   CHO-COH-CH2OH  
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if lowest -OH is on the right   D molecule  
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if lowest -OH is on the left   L molecule  
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fructose   has ketone  
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glucose   alternates but mostly OH on rght  
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galactose   2 in the middle are the same  
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mannose   first two are the same  
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alpha   C1 is in axial position which is less favored bcuz sterically hindered  
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beta   C1 is equitorial position (up); lower E so favored  
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glycosidic rxns   hemiacetal (monosaccharide in chair formation) + alcohol = acetal (alpha and beta)  
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Disaccharides   two monosaccharides; maltose, sucrose, lactose  
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maltose   glucose and glucose  
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sucrose   fructose and glucose  
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lactose   glucose and galactose  
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Polysaccharides   long chains of mono; starch, glycogen, cellulose  
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cellulose   1,4 beta linkage; cant be digested by animals  
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starch and glycogen   E in plants and animals respectively; 1,4 and 1,6 alpha linkages  
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