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Chapter 4
| Question | Answer |
|---|---|
| Isomers | variation in the structure of organic molecules with the same molecular formula |
| 3 types of isomers | Structural isomers, geometric isomers, enantiomers. Their different structures lead to different functions. |
| Structural isomers | differ in the covalent arrangement of their atoms, change in distribution of atoms around the carbon chain. Can be formed by exchanging two non-similar functional groups anywhere on the chain. |
| Geometric isomers | differ in their spatial arrangement around a C=C bond. Only with double bonds because rotation is not possible around double bonds. |
| Enantiomers | Must be built out of four different atoms built around an assymetric (chiral) carbon. Formed by changing the adjacent two atoms on a chiral carbon. |
| Trans | opposite/accross the carbon chain. |
| Sis | on the same side of the carbon chain. |
| Functional groups | groups of atoms frequently attached to the carbon skeletons of organic molecules. |
| Hydroxyl Group | -OH Alcohols (including sugars) Polar due to oxygen's electronegativity |
| Carbonyl | C=O aldehyde-carbonyl group at end of carbon chain, paired with an H ketone-carbonyl group nested inside the carbon chain |
| Carboxyl | -COOH Tends to act as an acid and donate H+ by ionizing into -COO- and H+ |
| Amino group | -NH2 Amines (nitrogen containing) Tends to act as a base by ionizing with water to form NH3+ OH- |
| Sulfhydryl group | -SH Important for protein stabilization by formation of S-S bridges |
| Phosphate Group | -PO4^(2-) Goes into ATP (cell fuel) Usually very reactive because of extreme polarity. The extra 2 oxygens are dying for electrons and passing them around. It WANTS electrons |