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MCET210

Midterm

TermDefinition
Initiation, Propagation, and Termination The three steps addition polymerization
Ethylene X = H
Propylene X = CH3
Vinyl Chloride X = Cl
Styrene X = Octagon
(Σ Ni * Mi) / Σ Ni Formula for Number Average Molecular Weight
∑(Ni Mi^2) / ∑(Ni Mi) Formula for Weight Average Molecular Weight
Ni Number of Molecules
Mi Molecular Weight
Mn Number Average Molecular Weight
Mw Weight Average Molecular Weight
Narrow Molecular Weight Distribution Most polymer chains are similar in size; a small range of difference in weight
Broad Molecular Weight Distribution There is a significant range of difference in weight between polymer chains
Mn/Mi Formula for Degree of Polymerization
Thermoplastic Can be melted, and reformed, and melted again. Created by addition and condensation reactions.
Thermoset Can be molted, but once melted, it cannot go back. Created only by condensation reactions.
Free Radical Catalyst This kind of catalyst has a broad molecular weight distribution, and is easier and cheaper to process.
Coordination Catalyst This kind of catalyst has a narrow molecular weight distribution, is more difficult to process, but has more consistent properties.
Condensation Polymerization A chemical reaction in which molecules combine to form water, and condenses out a simple substance.
Properties, Environmental Safety, and Chain Length The impacts of byproducts on the condensation reaction
Increased Conductivity, Swelling/Shrinkage, Increased Ductility The impacts of moisture on polymer properties.
Oligomer Stage The first stage of thermoset polymerization
Gelation Stage The second stage of thermoset polymerization
Crosslinking Stage The final part of thermoset polymerization
Semi-Crystalline Polymer This polymer has a higher density than its counterpart, resulting in lower free volume, and lower specific volume
Amorphous Polymer This polymer has a lower density than its counterpart, resulting in higher free volume, and higher specific volume
Higher Crystallinity These kinds of polymers have a higher tensile strength, higher thermal stability, and a distinct melting temperature
Lower Crystallinity These kinds of polymers have a higher impact resistance, higher flexibility, and no distinct melting temperature
Glass Transition Temperature The polymer goes from a hard, glassy state, to a soft, rubbery state when this temperature is reached
Melting Temperature The polymer goes from a soft, rubbery state to a liquid state when this temperature is reached. This is also when crystalline regions start to break down
Clamping This is the first step in injection molding; the mold is closed
Injection This is the second step in injection molding; the molten plastic is injected into the mold cavity
Dwelling This is the third step in injection molding; pressure is maintained to fill the mold
Cooling This is the fourth step in injection molding; the part cools and solidifies in the mold
Mold Opening This is the fifth step in injection molding; the mold opens
Ejection This is the final step in injection molding; the solidified part is ejected from the mold
Cold running This method of injection mold is cheap, but adds scrap and needs a finishing operation
Hot running This method of injection mold is expensive, but reduces scrap and yields a fully finished part
Landfills The most common way to dispose of waste, occupies a lot of space, but are highly regulated to promote anerobic breakdown
Incineration This method significantly reduces waste volume, methane emissions, and can even recover energy from waste, but can cause unwanted gas emissions
Sortation This process reduces the amount of waste that goes to landfills and incinerators, by taking potential recyclables out of waste
Recycling This process reuses old plastics, metals, and paper to create new products
Created by: Tsar Pasta
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