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Bio 458 Final

Plant Biochemistry final material

TermDefinition
Glyphosate Widely used herbicide that functions by preventing ESPS synthase in the Shikimate pathway
Flavones C4 carbonyl group with no hydroxyl groups, used for signaling and UV protection
Isoflavonoids Flavones with the aromatic ring branch on carbon 3 of the carbonyl group
Flavonol Hydroxyl group on carbonyl carbon 3, UV protection and antioxidant in humans
Anthocyanins Flavynium ion (positive charge), Aglycone without glycosylation, anthocyanidin with glycosylation
Tannins High molecular weight (big), protein binding due to aromatic rings. Antimicrobial and herbicide defense. Hydrolysable or Condensed forms
Isoprenoids Hydrocabrons based off of 5 carbon isoprene units,
Mevalonate pathway Cytosolic, 3x acetyl CoA -> mevalonate acid -> isopentenyl pyrophosphate -> dimethylallyl pyrophosphate (DMAPP) (using IPP isomerase)
Deoxy xylulose pathway in plastids, mono, di and tetra formed. Pyruvate and glyceraldehyde-3-P to produce IPP and DMAPP. Key enzyme: deoxylylose phosphate synthase (
Terpene synthases form cyclizations of terpene precursors
Hemiterpenes Volatile compound released from leaves for heat stress (blue mountains)
Monoterpenes and sesquiterpenes function direct defense against insects, secondary defense (wasps)
Cyanogenic Glycosides Glucosides that release CN when sugar is removed
Glucosinolates thioglucosides or mustard oils,
Myrosinase Hydrolyzes glycosinolates into isothiocyanate, activity prevented by cleaving sulfate from substrate
Shikimate acid pathway makes aromatic amino acids
Salicylic Acid used in aspirin, signal in resistance against plants. A phenolic
Salicylate phenolic glycosides willow and poplar, prevent herbivory a phenolic
Methyl benzoate coordination of circadian rhythm through timed release of volatile, a phenolic
Phenolic methyl esters Used as a fragrance in roses,
Hydroxycinnamic acids and esters Carboxylic acid connected along a C3-C6 bridge to a phenol
Coniferyl benzoate Type of Hydroxycinnamic acid: Feeding deterrent in aspen and poplar buds
Chlorogenic acid Type of Hydroxycinnamic acid: Feeding deterrent,
Sinapine Type of Hydroxycinnamic acid: used for UV protection in canola
Lignans Secondary metabolite, two phenylpropanoids connected with a C3-C6 bridge
Flax seed lignan estrogen mimic in diet
Plicatic acid Rotting resistance in redwoods
Pinoresinol Heartwood, rotting resistance
Coumarins intramolecular esters of p-coumaric acid, characterized by a lactone ring (carboxylic acid in a ring)
furanocoumarins (psoralin, xanthotoxin) Phototoxins, acivated by UV light, cause blistering
Stillbenes two aromatic rings connected with a 2 carbon bridge. p-coumaric a. plus 3x malonyl-CoA and using stillbene synthase
Phenolic Aromatic ring with at least one OH group
Phenylpropanoid Phenyl with a three carbon tail
Lignin Highly branched phenolic polymer
G-Lignin Guaiacyl, only kind that can be eaten
S-Lignin Syringyl
Diterpenes 20 carbon, 4 isoprenoid units
Gibberellins diterpenes promoting shoot growth
Oleoresin primary plant defence against mountain pine beetle
frontalin (male) verbenol (female,) exo-brevicomin (both sex) Hormones produced by beetles to attract
ipsendiol, verbenone repellent signals produced by beetles
Triterpenes 2x FPP synthesized with squalene synthesis
Azadirachtin tri-terpene derived toxin, contains limonoids
Cucurbitacin most bittere compound in the world, tri-terpene derived toxin
Sterol Triterpene with 4 rings and a 3' OH group
Saponins Glycosylated tri-terpenes, (have a sugar) example yamonin from yam
Cardiac glyosides Saponin that affects the muscles
Tetraterpenes 2 x GGPP = 40 C (phytoene synthase)
Beta-carotene vitamin A precursor
Golden rice GMO to produce beta carotene
Polyterpenes High molecular weight terpenes, includes latex and rubber
Created by: Ewilks12
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