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Bio 458 Final
Plant Biochemistry final material
| Term | Definition |
|---|---|
| Glyphosate | Widely used herbicide that functions by preventing ESPS synthase in the Shikimate pathway |
| Flavones | C4 carbonyl group with no hydroxyl groups, used for signaling and UV protection |
| Isoflavonoids | Flavones with the aromatic ring branch on carbon 3 of the carbonyl group |
| Flavonol | Hydroxyl group on carbonyl carbon 3, UV protection and antioxidant in humans |
| Anthocyanins | Flavynium ion (positive charge), Aglycone without glycosylation, anthocyanidin with glycosylation |
| Tannins | High molecular weight (big), protein binding due to aromatic rings. Antimicrobial and herbicide defense. Hydrolysable or Condensed forms |
| Isoprenoids | Hydrocabrons based off of 5 carbon isoprene units, |
| Mevalonate pathway | Cytosolic, 3x acetyl CoA -> mevalonate acid -> isopentenyl pyrophosphate -> dimethylallyl pyrophosphate (DMAPP) (using IPP isomerase) |
| Deoxy xylulose pathway | in plastids, mono, di and tetra formed. Pyruvate and glyceraldehyde-3-P to produce IPP and DMAPP. Key enzyme: deoxylylose phosphate synthase ( |
| Terpene synthases | form cyclizations of terpene precursors |
| Hemiterpenes | Volatile compound released from leaves for heat stress (blue mountains) |
| Monoterpenes and sesquiterpenes function | direct defense against insects, secondary defense (wasps) |
| Cyanogenic Glycosides | Glucosides that release CN when sugar is removed |
| Glucosinolates | thioglucosides or mustard oils, |
| Myrosinase | Hydrolyzes glycosinolates into isothiocyanate, activity prevented by cleaving sulfate from substrate |
| Shikimate acid pathway | makes aromatic amino acids |
| Salicylic Acid | used in aspirin, signal in resistance against plants. A phenolic |
| Salicylate phenolic glycosides | willow and poplar, prevent herbivory a phenolic |
| Methyl benzoate | coordination of circadian rhythm through timed release of volatile, a phenolic |
| Phenolic methyl esters | Used as a fragrance in roses, |
| Hydroxycinnamic acids and esters | Carboxylic acid connected along a C3-C6 bridge to a phenol |
| Coniferyl benzoate | Type of Hydroxycinnamic acid: Feeding deterrent in aspen and poplar buds |
| Chlorogenic acid | Type of Hydroxycinnamic acid: Feeding deterrent, |
| Sinapine | Type of Hydroxycinnamic acid: used for UV protection in canola |
| Lignans | Secondary metabolite, two phenylpropanoids connected with a C3-C6 bridge |
| Flax seed lignan | estrogen mimic in diet |
| Plicatic acid | Rotting resistance in redwoods |
| Pinoresinol | Heartwood, rotting resistance |
| Coumarins | intramolecular esters of p-coumaric acid, characterized by a lactone ring (carboxylic acid in a ring) |
| furanocoumarins (psoralin, xanthotoxin) | Phototoxins, acivated by UV light, cause blistering |
| Stillbenes | two aromatic rings connected with a 2 carbon bridge. p-coumaric a. plus 3x malonyl-CoA and using stillbene synthase |
| Phenolic | Aromatic ring with at least one OH group |
| Phenylpropanoid | Phenyl with a three carbon tail |
| Lignin | Highly branched phenolic polymer |
| G-Lignin | Guaiacyl, only kind that can be eaten |
| S-Lignin | Syringyl |
| Diterpenes | 20 carbon, 4 isoprenoid units |
| Gibberellins | diterpenes promoting shoot growth |
| Oleoresin | primary plant defence against mountain pine beetle |
| frontalin (male) verbenol (female,) exo-brevicomin (both sex) | Hormones produced by beetles to attract |
| ipsendiol, verbenone | repellent signals produced by beetles |
| Triterpenes | 2x FPP synthesized with squalene synthesis |
| Azadirachtin | tri-terpene derived toxin, contains limonoids |
| Cucurbitacin | most bittere compound in the world, tri-terpene derived toxin |
| Sterol | Triterpene with 4 rings and a 3' OH group |
| Saponins | Glycosylated tri-terpenes, (have a sugar) example yamonin from yam |
| Cardiac glyosides | Saponin that affects the muscles |
| Tetraterpenes | 2 x GGPP = 40 C (phytoene synthase) |
| Beta-carotene | vitamin A precursor |
| Golden rice | GMO to produce beta carotene |
| Polyterpenes | High molecular weight terpenes, includes latex and rubber |