Organic Chemistry Basics
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organic chemistry | chemistry related to the compounds containing carbons
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funcational group | an atom or group of atoms within a molecume that shows a characterisitic set of predictable physical and chemical behaviors
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alcohol group | a compund containing an -OH group bonded to a tetrahedral carbon atom
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hydroxyl group | an -OH group bonded to a tetrahedral carbon atom
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amine | an organic compund in which 1,2 or 3 hydrogens of ammonia are replaced by carbon groups of RNH2 OR R2NH OR R3N
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amino group | an -NH2, RNH2, OR R3N group
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carbonyl group | a C=O group
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aldehyde | a compound containing a carbonyl group bonded to a hydrogen a -CHO group
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ketone | a compound containing a carbonyl group bonded to 2 carbon groups
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carboxyl group | a -COOH group
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ester | a derivation of carboxylic in which the H of the carbon group
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alkane | a saturated hydrocarbon whose carbon atoms are arranged in a chain
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hydrocarbon | a compound that contains only carbon and hydrogen atoms
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saturated hydrocarbon | a hydrocarbon that contains only C-C bonds
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aliphatic hydrocarbon bonds | an alkane
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line angle formula | an abbreviated way to draw structure formulas in which each vertex and line terminus represents a carbon atom and each line represents a bond
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consitutional isomers | compounds with the same molecular formula but a different connectivity of their atoms
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alkyl groups | a group derived by removing a hydrogen from an alkane given the symbol R
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R- | a symbol used to represent an alkyl group
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cycloalkane | a saturated hydrocarbon that contains carbon atoms boned to form a ring
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conformations | any 3-D arrangement of atoms in a molecule that results from rotation about a single bond
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equatorial position | a position on a chair conformation of a cyclohexane ring that extends from the ring roughly perpendicular to an imaginary axis of the ring
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axial position | a position on a chair confromation of a cyclohexane ring that extends from the ring prallel to the imaginary axis of the ring
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cis-trans | isomers that have the same connectivity of their atoms but a different arrangement of their atoms in space due to the presence of either a ring or a C=C
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sterocenter | tertahedral atoms most commonly carbon at which exchange of 2 groups produces a stereoisomer
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configuration | refers to the arrangment o fatoms about a stereocenter that is the reative arrangment of parts of a molecule in space
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stereoisomer | isomer that have the same connectivity of their atoms but different orientation of their atoms in space
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alkene | an unsaturated hydrocarbon that contains a C=C
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alkyne | an unsaturated hydrocarbon that contains a triple C C bond
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Termal Cracking | a saturated hydrocarbon that is converted into an unsaturated hydrocarbon plus H2
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cycloalkenes | number of carbon atoms of the ring = bond 1 and 2
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Terpene | a compund whose carbon skeleton can be divided into two or more units identical to 5 carbon skeleton of isoprene
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Essential oils | highly fragrant oils from plants (rose, fressia, etc)
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regioselective reaction | a reaction in which one direction of bond formation or bond breaking occurs in preference to all other directions
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markovinkov's rule | in the addition of HX or H2O to alkene Hydrogens add to the carbon of the C=C having a greater humber of Hydrogens
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reaction mechanism | a step by step description of how a chemical reaction occurs
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carbocation | a species containing carbon atoms with only 3 bonds to it and bearing a positive charge
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hydration | addition of water
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oxonium ion | an ion in which oxygen is bonded to 3 other atoms and bears a positive charge
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catalytic reducation/ catalytic hydrogenation | the conversion of an alkane involves reducation by hydrogen in teh presence of a catalyst
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polymer | many parts any long chain molecule synthesized by bonding together many single parts called monomers
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monomer | single part, simplest nonredundant unit from which a polymer is synthesized
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peroxide | any compund that contains an -O-O- bond as for example hydrogen peroxide H-O-O-H
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aromatic compunds | benzene or one of its derivatives
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arene | a compund contian one or more benzene rings
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aryl group | a group derived from an arene by removal of an H and given the symbol Ar-
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Ar- | The symbol fused for aryl group
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Resonance hybid | a molecule best decribed as a composite of 2+ Lewis structures
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contributing structure | each individual lewis structure
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phenyl group | C6H15 aryl group derived by removing an Hydrogen atom from a benzene
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Autoxidation | ocidation requiring oxygen and no other reactant
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Active figure | autoxidation is a radical chain reaction vonverting hydrocarbons to a a hyroperoxide
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Chain length | number of times the cycle of chain propagation steps repeats
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Diol | a compound containing 2 -OH groups
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Triol | a compound containing 3 -OH groups
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Glycol | a compound with hydroxyl groups on adjacent carbons
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hydrogen bonding | Dipole-Dipole bond, between electronegative atoms and a hydrogen bonded to another electronegative atom
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dehydration | elimination of molecule of water from an alcohol, OH is removed from 1 C and H is removed from the adjacent C
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ether | a compund containing an oxygen between 2 atoms
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cyclic ether | an ether in which the ether oxygen is one of the atoms of the ring
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thiol | an -SH (sulfhydroyl group) bonded to a tetrahedral carbon atom
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mercaptan | a common name for any molecule containing an -SH group
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electronegativity | electons pulling ability on a molecule
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polarity | how equally bonding electons are shared between atoms, effects solubility, melting and boiling points
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covalent bonding | sharing of pairs of electrons
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ionic bonding | electrostative bond between 2 oppositely charged ions
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sigma bonding | 2 atoms are held together by the forces operating between them and a pair of elections shared by them the electon pair occupies an orbital
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pi bond | a conhesive interaction between to atoms and a pair of elections that occupy and an orbital located in 2 regions parallel
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free radical | a compound containing an unpaired electron
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Diradical | a compound that contains 2 unpaired electrons (oxygen)
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Monoterpene | 2 Isoprenes
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Sesquiterpenes | 3 Isoprenes
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Diterpenes | 4 Isoprenes
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Triterpenes | 6 Isoprenes
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Tetraterpenes | 8 Isoprenes
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Wohler | Made an organic out of 2 inorganics
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Fredrick.Kekule | Redefined organics how we know know it and found the benzene ring
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Markovinkov | rule of bonding H go towards more H's in reaction for stability
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L. Pauling | motion within benzene rings
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Created by:
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