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CHEM UNIT 2 PAST PAP Test

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1.
Which intermolecular forces exist between molecules of ethoxyethane?
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2.
The best piece of apparatus to accurately measure out 10.0 cm3 is a
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3.
How many moles of iodine were present in the solution of the iodine at the start of the experiment?
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4.
By considering the hydrogen bonding on these two solvents, suggest why 2-chlorobutane is more soluble in ethanol than in water.
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5.
Which of the terms above best describes what happens to the chlorine in the following reactions? Cl2(g) + H2O(l) → HCl(aq) + HOCl(aq)
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6.
Calcium nitrate decomposes like magnesium nitrate, higher temperature. Explain why the two nitrates have different stability to heat.
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7.
Which of these metal hydroxides is the most soluble in water?
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8.
The half-equation for the oxidation of ethanol is CH3CH2OH + H2O → CH3COOH + 4H+ + 4e- . to write a full equation for the overall reaction between acidified dichromate(VI) ions and ethanol.
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9.
Calculate whether the sulfur dioxide in this sample of air was within this limit. One mole of sulfur dioxide has mass 64.1 g.
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10.
In the reaction between Ag+(aq) ions and Fe2+(aq) ions, what would be the effect of increasing the concentration of Ag+(aq) ions? Ag+(aq) + Fe2+(aq)
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11.
One product of the reaction with potassium iodide is hydrogen sulfide, H2S. How does this show that iodide ions are more powerful reducing agents than bromide ions?
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12.
What colour would phenolphthalein turn at the end-point in this titration?
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13.
Butan-1-ol and three other alcohols, X, Y and Z, are isomers. Give TWO make when any one of the alcohols reacts with sodium.
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14.
Explain how a catalyst speeds up the rate of a reaction.
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15.
To identify the formation of the product when propan-1-ol has been partially oxidized, you can look for absorptions in the IR spectrum at absorption range
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16.
100 m3 air were passed through 100 cm3 I2, conc 0.0100 mol dm–3. The remaining iodine titrated with Nathiosulfate and reacted with ...
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17.
What is the oxidation number of nitrogen in ammonia, NH3?
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18.
Explain why the HNH bond angle is less than that for FBF.
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19.
Which of the following bond angles occur in a molecule of ethanol, C2H5OH?
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20.
Which of the following has dipole-dipole interactions between its molecules, but no hydrogen bonding?
A.
Provides alternative mechanism / route / pathway (1) Of lower activation energy (1) Hence a greater proportion of molecules can react (at a given T)
B.
I2 at start = 1 x 10-3 / 0.001 (mol)
C.
A pipette.
D.
104.5° and 109.5°
E.
3 electron pairs around central B atom but 4 electron pairs around central N
F.
12.60 cm3 of sodium thiosulfate, concentration 0.100 mol dm–3.
G.
Mg2+ / Magnesium ion smaller or fewer electron shells / greater charge density (1)OR Magnesium ion has same charge (as calcium ion) but is smaller (1) Causes more polarisation /distortion of nitrate/ anion (electron clouds) / N―O (bond)(1)
H.
Colourless.
I.
Effervescence / fizzing / bubbles (of colourless gas) (1) Mixture gets hot (1)
J.
disproportionation
K.
Rate of reaction increases, yield of Fe3+(aq) increases.
L.
Hydrogen iodide, HI
M.
Mass SO2 in 100 m3 =(64.1 x 3.70 x 10-4 ) (1) Mass SO2 in 1 m3 = 64.1 x 3.70 x 10-4 /100 = 237(.2) x 10-6 g = 2.37 x 10-4g (1) (= 237.2 / 237 / 240 μg)
N.
-3
O.
Energy must be at least EA for successful collision / for reaction (1) OR So more collisions have sufficient energy to react(1)
P.
3 CH3CH2OH + 2Cr2O72- + 16H+ → 3CH3COOH + 4Cr3+ + 11H2O ,3:2 ratio.
Q.
Water has 2 hydrogen bonds per molecule (on average) whereas ethanol only has 1 (1) ALLOW Water has more hydrogen bonds (per molecule) than ethanol Needs more energy to break H bonds in water (so less soluble) / H bonding
R.
Instantaneous dipole – induced dipole and permanent dipole – permanent Dipole.
S.
Barium hydroxide.
T.
To monitor whether all of the sample of propan-2-ol has been oxidized, you can look for.
Type the Answer that corresponds to the displayed Question.
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21.
This question is about boron and nitrogen compounds. Draw and name the shape of a boron trifluoride, BF3, molecule. Suggest the FBF bond angle.
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22.
Cl2(g) + 2Na(s) → 2NaCl(s)
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23.
The ability of a liquid to flow is linked to the strength of its intermolecular forces. Suggest which of these liquids flows the slowest when poured.
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24.
Which list below shows the compounds in order of increasing boiling temperature?
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25.
The hydroxide ion is acting as
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26.
Ammonia has the formula NH3. Its HNH bond angle is less than the FBF bond angle in boron trifluoride. Estimate the HNH bond angle in NH3.
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27.
What type of species forms when a bond breaks homolytically?
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28.
What colour would the mixture be after it was heated under reflux?
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29.
What volume of 0.200 mol dm–3 hydrochloric acid solution was added by the end-point?
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30.
The volume of barium hydroxide required was

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