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chapter 1

Quiz yourself by thinking what should be in each of the black spaces below before clicking on it to display the answer.
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Question
Answer
What are two components to an atom their components and unit of atom   1.nucleus:protons and neutron=atom =mass 2.electron cloud:electrons= atom volume  
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Elements in same row and column have same?   Row(period): size Column(group): electronic and chemical properties  
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Orbitals bw first row vs Second row   first: one orbital, shell 1s second: filled first shell of e-, 4 orbitals to accept add of e-. one 2s orbital and three 2p orbital  
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Group number represents number of?   valence e-  
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different e-: p: n:   e: ions p:elements n: isotopes  
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Define isomer   different molecules have same molecular formula  
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S orbital size, number of orbitals and e- fit   sphere, 1, 2e-  
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P orbital size, number of orbitals and e- fit   dumnbell,3, 6e-  
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d orbital size, number of orbitals and e- fit   4 leaf clover, 5, 10 e-  
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ionic vs covalent bodning   i: transfer e- bw differing electronegative elements c: sharing e- bw 2 nuclei  
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second row bonding rules   1-3 group elements= corresponding bonds 4+ group elements= octet  
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Fish hook bw double headed arrows   fish: moving one e-, arrow= movment of e-  
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method to find amount of bonds in a element   1=3 groups correspondence, 4+ group want octet so 8- valence e-  
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method of lone pairs   valence e- - 4  
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Frormal charge=   # ve- -# of owned atoms  
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owned atoms=   # of unshared e- + 1/2(shared e-)  
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shared vs unshared e-   un: # of e- in a lone pair, shared: bonded e-  
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Longest/shortest element in bond length: longest: Fr, shortest: He   Fr, shortest: He  
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Bond angle   determine shape around any atom bonded to 2 other atoms  
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geometry of atom determined by   #of groups (atoms or lone pair)  
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groups definition according to bond angle   atoms or lone pair  
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Second row arrangements geometry and bond angle for 2,3,4 groups   2:linear, 180degrees, 3: trigonal planar, 120d, 4: tetrahedral, 109.5d  
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Bond Lenth   average distance bw center of two bonded nuclei in angstroms (pm)  
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Bond length conversion across column   BL increase down column as atom size increases  
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Bond length conversion across row   BL decrease across row as atom size decreases  
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Constitutional isomer   same molecular formula but different dot connects  
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Third row exceptions of octet rule   B= 6e-, Be= 4e-, highly reactive  
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resonance   two lewis structure having same atomic placing but differ e- arrangement  
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double head arrow in resonance   seperate r structures  
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Resonance rules   change multiple bond and nonbonded e-, NOT atom placement and single bonds, same # of unpaired e-, valid l structures  
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polar   one polar bond or two or more bond dipoles that reinforce  
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nonpolar   no polar bond or two or more bond dipoles that cancel bc of equal and opposite in direction  
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