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Ch 1-4

Quiz yourself by thinking what should be in each of the black spaces below before clicking on it to display the answer.
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Question
Answer
Cation   Positively charged (less electrons)  
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Anion   Negatively charged (more electrons)  
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The more polar the bond...   the more electronegative the bond  
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What elements have the highest electronegativity?   F-4 O-3.5 N, Cl-3.0 Br-2.8  
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What elements have the same electronegativity as C?   S and I 2.5  
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List the elements with electronegativity of 2.4 and 2.2   Se, Au (2.4) Ru, Os, Pd, Ir, Rh, Pt (2.2)  
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List the elements with electronegativity of 2.1 and 2.1   P, At, H, Te (2.1) Po, As, B (2.0)  
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$What is the name, hybridization and bond angle for a four bond C   Tetrahedral, sp3, 109  
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$What is the name, hybridization and bond angle for a three bond C   Trigonal planar, sp2, 120  
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$What is the name, hybridization and bong angle for a two bond C   Linear, sp, 180  
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$What is the length of a single C-C bond and the length of the C-H bonds   C-C: 154pm C-H: 110pm  
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$What is the length of a double C-C bond and the length of the C-H bonds   C-C: 133pm C-H: 108pm  
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$What is the length of a triple C-C bond and the length of the C-H bonds   C-C: 120pm C-H: 106pm  
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$What is the angle of a N-H bond with one group of valence electrons   107  
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$What is the angle of a O-H bond with two groups of valence electrons   104  
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$What is the formula for dipole moment   u=difference in electronegativity (Q) x distance separating charges (r)  
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Rule of electron movement   In multiple bond, electron movement is always towards most electronegative atom  
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What is the length of a typical C-O bond   135pm  
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What is the length of a typical C-O double bond   120pm  
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Rule of resonance form drawing   any three atom grouping with a p orbital on each atom as two resonance forms  
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What is a Bronsted-Lowry acid   a substance that donates a proton (H+)  
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What is a Bronsted-Lowry base   a substance that accepts a proton (H+)  
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What is a conjugate acid   The product that results when a B-L base gains a proton  
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What is a conjugate base   The product that results when a B-L acid loses a proton  
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Give the equation for the acidity constant, Ka   HA + H2O -> A- + H3O+ Ka=Keq[H2O]=[H3O+][A-]/[HA]  
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The stronger the acid (larger Ka)   the smaller the pKa  
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A Lewis acid   accepts an electron pair  
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A Lewis base   donates an electron pair  
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What direction do dipole arrows go   positive to negative  
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Electronegativites between 0 and 0.5 are   nonpolar covalent  
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Electronegativites between0.5 and 2 are   polar covalent  
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Electronegativities greater than 2 are   ionic  
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What is the formula for alkanes   CnH2n+2  
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Constitutional isomers   differ in their connections between atoms  
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Conformations are   rotation of sigma bonds  
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What is the formula for cycloalkane   CnH2n  
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Cis   on the same side  
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Trans   across  
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Stereoisomers   atoms connected in same order but differ in three-dimensional orientation  
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  cyclopropane  
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  cyclobutane  
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  cyclopentane  
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  cyclohexane  
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