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4th-exam

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Vocabulary
Definition
Electrochemistry   The study of the relationship between electricity and chemical reactions  
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Electrolytic Cells   Are nonspontaneous chemical reactions; consumes electrical energy from an external source to cause a nonspontaneous redox reactions to occur  
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Voltaic Cells   Also called galvanic cells are spontaneous chemical reactions; energy released during a spontaneous reaction generates electricity  
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Cathode   Is negative in electrolytic cells and positive in voltaic cells; occurs in reduction reaction  
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Anode   Is positive in electrolytic cells and negative in voltaic cells;occurs in oxidation reaction  
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Metallic Conduction   Both types of cells contain two electrodes connected to an external circuit that provides an electrical connection between systems  
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Ionic Conduction   When circuit is closed, electrons flow from the anode to the cathode; electrodes are connected by an electrolyte, which is an ionic substance or solution that allows ions to transfer between the electrodes, maintaining the system’s electrical neutrality  
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Standard Electrode Potential   The potential of a half-reaction measured against the standard hydrogen electrode under standard conditions  
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Standard Hydrogen Electrode (SHE)   consists of a strip of platinum wire in contact with an aqueous solution containing 1 M H+, which is in equilibrium with H2 gas at a pressure of 1 atm at the Pt-solution interface  
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Coulomb   Is the amount of charge that passes a given point when a current of one ampere flows from one second  
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Battery   A galvanic cell that contains all the reactants needed to produce electricity  
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Fuel Cell   A galvanic cell that requires a constant external supply of one or more reactants in order to generate electricity  
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