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Chem II Lab - spring 2011

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Hydrocarbon   organic compounds that contain only hydrogen and carbon atoms  
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Chain Aliphatic Hydrocarbons   compounds consisting of carbons linked either in a straight chain or in a branched chain  
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Cyclic Hydrocarbons   aliphatic compounds that have carbon atoms linked in a closed paragon (aka ring)  
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Alkanes   hydrocarbons which contain only carbon-carbon single bonds  
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Saturation of Hydrocarbons   Alkane- saturated Alkene- unsaturated Alkyne- unsaturated  
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Alkene   hydrocarbons which contain at least one carbon-carbon double bond  
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Alkyne   hydrocarbons which contain at least one carbon-carbon triple bond  
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Aromatic   cyclic hydrocarbons that contain a closed loop (sextet) of electrons  
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Hydrocarbons vs. Polar Solvents   hydrocarbons do not mix with polar solvents such as water or ethyl alcohol, but will mix with other organic non-polar solvents  
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Density of Hydrocarbons   density of hydrocarbons is less than water, therefore hydrocarbons float  
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Solubility of Hydrocarbons   hydrocarbons are not soluble in hemicawater  
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Chemical Reactions of Hydrocarbons   Combustion, Reaction with Bromine, Reaction with Sulfric Acid, and Reaction with Potassium Permangante  
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Combustion   All hydrocarbons participate in combustion, resulting in CO2 and O2 as products. Alkanes, Alkenes, and Alkynes burn with a yellow non-sooty flame. Aromatic burns with a black sooty flame.  
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Reaction with Bromine   Alkanes do not react.(addition rxn) Alkenes break their double bond and replace with 2 Bromines. Alkynes break their triple bonds and replace with 4 Bromines. **Brown-red to colorless rxn**  
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Aromatic Reaction with Bromine   aromatics undergoes a substitution reaction with Bromine in the presence of an Fe or AlCl3 catalyst.  
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Reaction with Sulfuric Acid   (addition rxn) Alkanes and Aromatics do not react. Alkenes break double bonds and replace with H and HSO4. Alkynes does the same but slower and in the presence of HgSO4. **cold to warm rxn**  
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Reaction with Potassium Permanganate   Alkanes, Alkynes and Aromatics do no react. Alkenes break their double bonds and replace with two OH and produces MnO2 and KOH. **purple to brown rxn (Alkene forms a glycol)  
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