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Chapter 12

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Question
Answer
What Is a Solution?   A homogeneous mixture of 2 or more substances.  
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What is a solute?   the substance present in the smaller amout.  
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What is a solvent?   Substance present in larger amount.  
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Exothermic   to release heat.  
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Endothermic   absorbs heat  
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Solubility   the measure of how much solute will dissolve at a specific temperature.  
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saturated solution   contains the maximum amount of solute that will dissolve in a given solution.  
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Unsaturated Solution   contains less solute the the solvent had the capacity to dissolve at a specific temperature  
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supersaturated solution   contains more solute than is present in a saturated solution at a specific temperature.  
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Crystallization   the process in which dissolved solute comes out of the solution and forms crystals  
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miscible   two liquids that are completely soluble in each other in all proportions  
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solvation   the process in which an ion or a molecule is surrounded by solvent molecules arranged in a specific manner.  
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Hydration   when water is the solvent  
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mole   number of grams/ molar mass  
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like dissolves like   two substances with similar intermolecular forces are likely to be soluble in each other.  
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concentration   is the amount of solute present in a given quantity of solution  
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percent by mass   mass of solute/mass of the solution x 100  
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mole fraction   Xa= moles of a/ sum of all components  
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molarity   moles of solute/Liters of solution  
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molality   moles of solute/mass of the solvent (kg)  
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Henry's Law   solubility of a gas in a liquid is proportional to the pressure of the gas over the solution c=kp  
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c   the concentration of dissolved gas (mol/L)  
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P   the pressure of gas over the solution (atm)  
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k   is the constant for each gas (mol/L.atm) that depends only on the temperature  
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colligative properties   properties that depend only on the number of solute particles in solution and not the nature of the solute particles  
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Vapor-Pressure Lowering   P1=x1p°1  
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P1   vapor pressure of solvent over a solution  
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X1   mole fraction of the solvent  
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P°1   vapor pressure of pure solvent  
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ideal solution   any solution that obeys Raoult's law  
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fractional distillation   a procedure for separating liquid components of a solution based on their different boiling points  
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boiling-point elevation   (delta Tb) the boiling point of the solution (Tb) minus the boiling point of the pure solvent (t0b) deltaTb=KbMi  
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Freezing-point depression   the freezing point of pure solvent (Tfo) minus the freezing point of the solution (Tf) DeltaTf=Kfmi  
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osmotic pressure   The pressure require to stop osmosis. pi=MRTi  
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Osmosis   is the selective passage of solvent molecules through a porous membrane from a dilute solution to a more concentrated one  
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Semipermeable membrane   allows the passage of solvent molecules but blocks the passage of solute molecules  
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M   molarity of the solution  
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R   the gas constant (0.0821L.atm/k.mol)  
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T   is the temperature in K.  
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Van't Hoff factor   actual number of particles in soln after dissociation/number of formula units initially dissolved in soln  
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colloid   is a dispersion of particles of one substance throughout a dispersing medium of another substance  
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volatile   have a measurable vapor pressure  
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nonvolatile   no measurable vapor pressure  
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isotonic   two solutions of equal concentration that have the same osmotic pressure  
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hypertonic   the more concentrated solution  
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hypotonic   the less concentrated soulution  
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crenation   process that causes cells to shrink and eventually to cease functioning  
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ion pairs   made up of one or more cations and one or more anions held together by electrostatic forces.  
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hydrophilic   water loving  
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hydrophobic   water-fearing  
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Tyndall Effect   the scattering of the visible light by colloid particles  
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Roault's Law   the vapor pressure of the solvent over a solution is given of the pure solvent and the mole fraction of the solvent in the solution.  
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