Entropy/Free Energy
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First Law of Thermodynamics | show 🗑
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Second Law of Thermodynamics | show 🗑
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Third Law of Thermodynamics | show 🗑
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How does temperature affect entropy? | show 🗑
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When will an increase in temp/energy have a greater impact? | show 🗑
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What affect does pressure have on entropy? | show 🗑
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show | equilibrium, because it is the lowest possible free energy point
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show | Wmax = G; maximum possible useful work obtainable from a process at constant temp/pressure; equal to the change in free energy
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What is deltaG? | show 🗑
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What is "wasted" energy? | show 🗑
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Reversible Process | show 🗑
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show | universe is different after cyclic process is performed; system returns to its original state, but surrounds has to furnish a net amount of work; all real processes are irreversible
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show | when gas+O2 combust, the energy in bonds spreads over the surroundings as thermal energy instead of being concentrated; the thermal energy is harder to use. the energy has become more disordered (increase in entropy) and less useful (energy crisis)
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deltaS of surroundings | show 🗑
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show | occurs without outside intervention
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show | depends on the number of positional microstates (spatial configurations) that yield a specific state
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show | deltaS of universe = deltaS of system + deltaS of surroundings; deltaS universe = -deltaG / T in K
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