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CHAPTER 12

Quiz yourself by thinking what should be in each of the black spaces below before clicking on it to display the answer.
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Question
Answer
show Calcium hydroxide, Ca(OH)2  
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Acid rain is formed when sulfur dioxide and oxides of nitrogen dissolve in rain water. Which problem is not caused by acid rain?   show
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show True  
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True or false; Acid rain contains sulfur dioxide which is formed when sulfur compounds burn in the air   show
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Sulfur is a common starting material for the Contact process. Name a source of sulfur   show
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Describe step 2, giving reaction conditions and a chemical equation. Reference to reaction rate and yield is not required   show
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show Bubbles Dissolves Blue solution  
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Dilute sulfuric acid is a typical acid. A student adds excess dilute sulfuric acid to a sample of solid copper(II) carbonate in a test-tube. Give the names of all products formed   show
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Concentrated sulfuric acid has different properties to dilute sulfuric acid. When concentrated sulfuric acid is added to glucose, C6H12O6, steam is given off and a black solid is formed. What type of reaction has occurred?   show
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Sulfuric acid is made by the Contact process. Sulfur is burned by spraying droplets of molten sulfur into air. Suggest and explain two advantages of using this method.   show
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Sulfur dioxide is more expensive than air. What is the three advantage of using an excess of air?   show
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show Moves equilibrium to left; Forward reaction exothermic;  
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The forward reaction is exothermic. The reaction is usually carried out at a temperature between 400 and 450 °C. (ii) What is the four effect on the rate of using a temperature below 400 Degrees C? Explain your answer.   show
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A low pressure, 2 atmospheres, is used. At equilibrium, about 98% SO3 is present. What is the effect on the position of equilibrium of using a higher pressure?   show
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show High yield at 2 atm;  
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Name the catalyst used in the Contact process   show
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Describe in three points how concentrated sulfuric acid is made from sulfur trioxide   show
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show Bleach Making wood pulp  
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One source of sulfur dioxide is burning sulfur in air. Describe how sulfur dioxide can be made from the ore zinc sulfide   show
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show Faster reaction rate More collisions per second Higher collision frequency fewer moles Molecules (of gas) on right Position of equilibrium shifts right Yield increases  
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show The reaction is too violent and too exothermic Produces mist and fumes of acid  
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Sulfuric acid is an important acid, both in the laboratory and in industry. Its manufactured in the Contact Process. it was made by heating metal sulfates and by burning a mixture of sulfur and potassium nitrate. Give a major use of sulfuric acid.   show
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When the iron(II) sulfate is heated strongly, further decomposition occurs. 2FeSO4(s) - Fe2O3(s) + SO2(g) + SO3(g) The gases formed in this reaction react with water and oxygen to form sulfuric acid. Explain how the sulfuric acid is formed.   show
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When a mixture of sulfur and potassium nitrate is burned and the products are dissolved in water, sulfuric acid is formed. The sulfuric acid formed by this method is not pure. It contains another acid. Deduce the identity of this acid.   show
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show 2KNO3 = 2KNO2 + O2  
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Sulfuric andHexanesulfonic acidis a strong acid. It has similar properties to sulfuric acid. Sulfonic acids are made from alkanes and oleum, H2S2O7. C6H14 + H2S2O7  C6H13SO3H + H2SO4 Describe how oleum is made from sulfur by the Contact process.   show
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show Add oleum to water  
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show Measure rate with named reactive metal, Mg, Zn Both fast reactions  
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show  
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Explain the terms strong acid   show
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Explain the terms weak acid   show
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The food additive E220 is sulfur dioxide. It is a preservative for a variety of foods and drinks. State two other uses of sulfur dioxide.   show
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show Burn or heat or react sulfur; In air oxygen  
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Sulfur dioxide is a reductant (reducing agent). Describe what you would see when aqueous sulfur dioxide is added to acidified potassium manganate(VII).   show
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Zinc blende is heated in air. Zinc oxide and sulfur dioxide are formed. Write the balanced equation for this reaction   show
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show Two reagents from named metal(s) more reactive to form zinc orcarbon monoxide  
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show Burns to form sulfur dioxide Acid rain Any problem associated with acid rain Sulfur dioxide is poisonous  
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Sulfur dioxide is made by spraying molten sulfur into air. The sulfur ignites and sulfur dioxide is formed. Suggest why molten sulfur is used in the form of a fine spray   show
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show Kills bacteria. Anti-oxidant Stops oxygen oxidising juice Prevents growth of bacteria  
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show Bleach Refrigerant Making wine Fumigant Insecticide Dyes  
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Describe how sulfur dioxide is changed into sulfur trioxide. Give the reaction conditions and an equation   show
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show It kills bacteria  
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show Its been used as a bleach  
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Define the term acid   show
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Suggest an explanation why sulfurous acid in contact with air changes into sulfuric acid.   show
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show Its been used as a bleach  
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How does Sulphur dioxide preserve food?   show
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show Bubble into (conc) sulphuric acid  
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Explain, mentioning both rate and percentage yield, why the temperature used in the Contact process is 450°C   show
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