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Chapter 13

Quiz yourself by thinking what should be in each of the black spaces below before clicking on it to display the answer.
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Term
Definition
gases   contain particles that are far apart, in random motion, and independent of one another  
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solids   contain particles very close in space and maintain a rigid shape; significant attractive forces exist between particles.  
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liquids   intermediate between gases and solids  
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evaporation or vaporization   escape of molecules from the liquid to the gas phase  
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condensation   when molecules from the liquid phase can escape to the vapor phase through evaporation, molecules in the gas phase can strike the surface of the liquid and return to the liquid phase.  
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vapor pressure   pressure exerted by a vapor in equilibrium with its liquid phase.  
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volatile liquids   very weak attractive forces between molecules; evaporate very rapidly at ambient temperature and have high vapor pressures as a result.  
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cohesive forces   exist between water molecules in a liquid.  
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adhesive forces   exist between water molecules and the walls of the container  
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convex   adhesive forces < cohesive forces  
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concave   adhesive forces > cohesive forces  
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normal boiling point   temperature when the vapor pressure is 1 atm  
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water   100 ºC  
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ether   35 ºC  
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ethyl alcohol   78 ºC  
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freezing/melting point   the temperature at which the solid phase of a substance is in equilibrium with its liquid phase.  
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heat of fusion   energy required to change 1 g of a solid at its melting point to a liquid  
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heat of vaporization   energy required to change 1 g of a liquid to vapor at its normal boiling point  
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ice melts   total energy = mass x heat of fusion  
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liquid water is warmed from 0° to 100°C   energy = mass x specific heat x ΔT  
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water evaporates   energy = mass x heat of vaporization  
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hydrogen bonds   one type of strong intermolecular force/attraction between molecules  
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london forces   arise from uneven, instantaneous charge distributions due to electron movement in nonpolar molecules.  
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hydrates   are solids that contain water molecules as part of their crystalline structure  
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% water   mass water/molar mass x 100  
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osmosis   process by which water flows through a membrane from a region of more pure water to a region of less pure water  
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reverse osmosis   process by which water flows through a membrane from a region of less pure water to a region of more pure water, due to the presence of an external stimulus (typically pressure)  
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