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Solubility
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Solubility
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The resulting solution is called |
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Gas over a liquid at a particular temp |
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a given gas dissolves in a given pressure of the gas in equilibrium with the liquid |
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as you increase the pressure linearly for a | Henry's Law
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Build up saturation of nitrogen, when you resurface to quickly, it comes out of solution in the jts and tissue, this is | The Bents or The Caisson's
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Henry's Law only applies for | constant temperatures
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as temperature increases gases dissolve | less
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Pressure independent function | Ostwald solubility Coefficient
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as the ratio of the amount of substance present in one phase compared with another, the two phase being equal volume and equilibrium | Partition Coefficients
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Which gas is more soluble in the blood:gas coefficients? N2O, ether, halothane What are there bld:gas coefficients | Ether (12)
Halothane(2.3)
N20(0.47)
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The greater the insolubility (more equilibrium or speed) | the quicker induction rate
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Advantage of N20 | has a quicker induction rate
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Disadvantage of N20 | can lead to diffusion hypoxemia (reverse of 2nd gas effect)
tx: extubate with 100% o2
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more soluble=more potent | oil:gas coefficient (effect)
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less anesthetic to achieve desired clinical effect | potency
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more insoluble=quicker induction rate | bld:gas coefficient(equilibrium or speed)
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which gas is more potent in bld | Ether
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which gas is more potent than ether | Halothane
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on the log scale with gas is most potent on pg 7 | methoxytilurane
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Oxygen dissolves in blood at | 0.003cc/100cc/mmHg partial pressure
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C02 dissolves in blood at | 0.067cc/100cc/mmHg partial pressure
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rate of change of a quantity of any time is proportional to the quantity at that time | exponential process
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process by which the molecules of a substance transfer through a layer or area such as the surface of a solution | Diffusion
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smaller molecules diffuse | faster
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rate of diffusion of a substance across a unit area is proportional to the concentration gradient | fick's law
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this is affected by solubility of gas diffusing into liquid medium | rate of diffusion
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Oxygen and Carbon Dioxide rates of diffusion are different therefore more likely to become | hypoxemic
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Do liquid or gases take longer to diffuse | liquids
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Diffusion Rate= Reciprocal of the square root of the molecular weight | Graham's Law
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what is Graham's law equation | 1/√MW
1 divided by the square root of MW=molecular wt
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Diffusion equation | (p1-p2)(area)(solubility)/
(memb. thickness)(√molecular wt)
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what is diffusion proportional to | tension gradient (p1-p2), solubility, and directly proportional to membrane area
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what is diffusion inversely proportional to | membrane thickness, the square root of MW of the substance diffusing
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usually occurs with a semi permeable membrane, this membrane is semi permeable to one or more solutes. | osmosis
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moles per liter | osmolarity
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moles per kilogram | osmolality
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osmotic pressure related to proteins | oncotic pressure
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body osmolarity is | 300mmol per liter
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difference in osmolar gradient | oncotic pressure
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depression of vapor pressure of a solvent is proportional to the molar concentration of solute (measurement of osmolarity) | Raoult's Law
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factors that effect osmolarity | osmotic pressure, freezing pt depression, vapor pressure reduction, and boiling pt elevation.
(colligative properties)
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a mixture which vaporizes in the same proportion as its constituent volume proportions | Azeotropes
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thermal state of a substance, determines whether heat will flow to or from the substance | Temperature
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a form of energy, transfer from hotter to cooler substance, energy is in the form of kinetic energy | heat
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SI unit of temperature | kelvins
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determined by general metabolic rate of person | heat production
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heat production= | 50 W/m²=80 Watts total
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four principle routes with typical heat losses | Radiation, Convection, Evaporation, Respiration
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what are the heat losses in percent | Radiation 40%
Convection 30%
Evaporation 20%
Respiration 10% (evaporation 8%,heating of air 2%)
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carries away heat, cooler object absorbs the heat. occurs in OR accounts for 50% heat loss | Radiation
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Adjacent layer of air is heated, that heated air rises carrying away heat. | Convection
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due to loss of latent heat of vaporization (liquid on the skin) as the liquid evaporates it sucks heat out of the body | Surface Evaporation
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small part of heat loss, accounts for 8% of humidifying inspired air | Respiration
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Inspiration of dry anesthetic gases may account for intra-op | hypothermia
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physiologic control of temp is mediated by | hypothalamus
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body temp below 35 degrees C | hypothermia
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fever, may be due to endogenous pyrogens or from bacterial infections | Pyrexia
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Succinylcholine and volatile anesthetics are known triggering agents for | malignant hyperthermia
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occurs when skin at or higher than 45 degrees for prolonged time | thermal burns
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quantity of heat required to increase the temperature of an object | Specific heat capacity
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SI unit of specific heat capacity | J/(kg k)
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amount of heat required to raise the temperature of a given object by 1 kelvin | heat capacity
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SI unit of heat capacity | J/K
Joules per degree of kelvin
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amount of heat required to raise the temperature 1 kilogram of a substance by 1 kelvin | specific heat capacity
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4.18 Joules = | 1 calorie
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4.18kJ= | 1 kilocalorie=1C
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calculated by knowing the specific heat comtent, mass, and temperature | body heat content
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change of state without change in temperature, requires energy | latent heat
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joules per sec | watts
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body generates how many watts? | 80
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energy used when a substance change state from a liquid to a gas | latent heat of vaporization
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the heat required to convert 1kg of a substance from one phase to another at a given temp. | specific latent heat
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SI unit for specific latent heat | Jkg^-1
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at temperature decreases the specific latent heat | increases
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N20 critical temperature is | 36.5
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critical temperature for 02 | -116 C
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ways to conserve energy use | humidified gases
circle circuit system
humidity conservation device
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humidity in upper trachea | 34mg/L (humidify air)
9.6 watts
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warming 02 | 2 watts
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universal gas law | pv=nRt
R=0.0821 L atm mol-¹K-¹
p=pressure
v=vol
n=#'s moles of gas
R=gas constant
T=temp(K)
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the total pressure exerted by a gaseous mixture is equal to the sum of the partial pressures of each individual component in a gas mixture. | Dalton's law
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SI units for pressure | pascals
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going form one force to another set of forces is called | Van de Waals Forces
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consists of identical particles of zero volume hypothetical gas | ideal gases
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equal vol of gases, at same temp. and pressure contain the same # of particles or molecules | Avogadro's Hypothesis
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one mole of ideal gas occupies | 22.4 L @STP
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how many liters of N20 is in a full tank | 1590
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the uptake of a volatile agent is increased when it is administered simultaneously with N20 | Second Gas Effect
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One mole of particles of solute in 22.4L produces | 101.35kPa (1atm)
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half life = | time constant * logℯ=time constant*0.693
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pressure= | force/area
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force= | pressure * area
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volume= | distance*area
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distance= | volume/area
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work= | pressuure*vol.
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