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Thermodynamics

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Term
Definition
enthalpy of formation   the enthalpy change when one mole of a compound is formed from its constituent elements under standard conditions, all reactants and products in their standards states  
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ionisation enthalpy   the standard enthalpy change when one mole of gaseous atoms is converted into one mole of gaseous ions each with a single positive charge  
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enthalpy of atomisation   the enthalpy change when one mole of gaseous atoms is formed from the element in its standard state under standards conditions  
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bond dissociation enthalpy   the enthalpy change when one mole of gaseous molecules each breaks a covalent bond to form two free radicals, averaged over a range of compounds  
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electron affinity   the standard enthalpy change when a mole of gaseous atoms is converted to a mole of gaseous ions, each with a single negative charge  
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lattice enthalpy   the standard enthalpy change when one mole of solid ionic compound is formed from its gaseous ions  
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enthalpy of hydration   the standard enthalpy change when water molecules surround one mole of gaseous ions  
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enthalpy of solution   the standard enthalpy change when one mole of solute dissolves completely in sufficient solvent to form a solution in which the molecules or ions are far enough apart not to interact with each other  
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Hess's Law   the overall enthalpy change for a reaction is independent of the route taken from reactants to products  
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