Chapter 8 - Phases and Phase Changes
Quiz yourself by thinking what should be in
each of the black spaces below before clicking
on it to display the answer.
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Condensed Phases | liquids and solids
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Liquids | have def volumes, can't be expanded/compressed, disorder, molecules can evaporate and diffuse
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Solutions | liquids can mix to form ____
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Miscibility | degree to which two liquids can mix
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Emulsion | when two immiscible liquids are shaken to make a homogeneous mixture
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Solids | strong attractive forces, molecules held tightly together, vibrate about fixed positions, dense shape/volume, crystalline or amorphous
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Crystalline | an ordered structure; 3-D geometric arrangement with repeating patterns
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Amorphous | like glass; no 3-D arrangement
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2 types of crystalline | metallic and ionic crystals
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Ionic Crystals | high bp and mp, poor conductivity, no discrete molecules, aggregates of ions
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Metallic Crystals | metal atoms packed tightly, single element, high mp and bp, strong covalent bonds
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Unit Cells | 3 types, simple cubic, body-centered cubic, and face-centered cubic
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Evaporation/Vaporization | liquid to gas; a cooling process
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Condensation | gas to liquid; pressure forces gas molecules back into liquid phase
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Vapor Pressure | equilibrium reached btwn vaporization and condensation. rates are equal
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boiling point | temp at which the vapor pressure equals the external pressure
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Fusion/Melting | solid to liquid; occurs at melting point
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solidification/crystallization/freezing | liquid to solid; occurs at freezing point
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Sublimation | solid to gas directly; dry ice
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Deposition | gas to solid directly
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Gibbs Function | G must be zero for an equilibrium so for sublimation, Gs=Gg
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Triple Point | point on phase diagram where all three phases are in equilibrium
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Critical Point | Point B where the temp and P causes there to be no distinction btwn liquid and gas
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Raoult's Law | one can determine the relationship btwn vapor pressure of vapor A and concentration of liquid A in soln
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Freezing-Point Depression | Tf= Kf(m); m is molality
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molality | mol solute/kg solvent
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Boiling-Point Elevation | Tb = Kb(m)
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Osmotic Pressure | pressure exerted to counterbalance tendency of water to flow across membrane; high to low concentration; = MRT, M is molarity
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Molarity | M; mol/L (n/V)
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