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Chapter 8 - Phases and Phase Changes

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Term
Definition
Condensed Phases   liquids and solids  
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Liquids   have def volumes, can't be expanded/compressed, disorder, molecules can evaporate and diffuse  
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Solutions   liquids can mix to form ____  
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Miscibility   degree to which two liquids can mix  
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Emulsion   when two immiscible liquids are shaken to make a homogeneous mixture  
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Solids   strong attractive forces, molecules held tightly together, vibrate about fixed positions, dense shape/volume, crystalline or amorphous  
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Crystalline   an ordered structure; 3-D geometric arrangement with repeating patterns  
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Amorphous   like glass; no 3-D arrangement  
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2 types of crystalline   metallic and ionic crystals  
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Ionic Crystals   high bp and mp, poor conductivity, no discrete molecules, aggregates of ions  
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Metallic Crystals   metal atoms packed tightly, single element, high mp and bp, strong covalent bonds  
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Unit Cells   3 types, simple cubic, body-centered cubic, and face-centered cubic  
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Evaporation/Vaporization   liquid to gas; a cooling process  
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Condensation   gas to liquid; pressure forces gas molecules back into liquid phase  
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Vapor Pressure   equilibrium reached btwn vaporization and condensation. rates are equal  
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boiling point   temp at which the vapor pressure equals the external pressure  
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Fusion/Melting   solid to liquid; occurs at melting point  
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solidification/crystallization/freezing   liquid to solid; occurs at freezing point  
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Sublimation   solid to gas directly; dry ice  
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Deposition   gas to solid directly  
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Gibbs Function   G must be zero for an equilibrium so for sublimation, Gs=Gg  
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Triple Point   point on phase diagram where all three phases are in equilibrium  
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Critical Point   Point B where the temp and P causes there to be no distinction btwn liquid and gas  
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Raoult's Law   one can determine the relationship btwn vapor pressure of vapor A and concentration of liquid A in soln  
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Freezing-Point Depression   Tf= Kf(m); m is molality  
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molality   mol solute/kg solvent  
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Boiling-Point Elevation   Tb = Kb(m)  
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Osmotic Pressure   pressure exerted to counterbalance tendency of water to flow across membrane; high to low concentration; = MRT, M is molarity  
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Molarity   M; mol/L (n/V)  
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