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Chemistry Ch.16

Quiz yourself by thinking what should be in each of the black spaces below before clicking on it to display the answer.
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Question
Answer
1) Identify a good buffer.   show
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2) Which of the following solutions is a good buffer system?   show
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show B) A solution that is 0.10 M HCN and 0.10 M LiCN  
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show C) A buffer resists pH change by neutralizing added acids and bases.  
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5) If the pKa of HCHO2 is 3.74 and the pH of an HCHO2/NaCHO2 solution is 3.11, which of the following is TRUE?   show
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show A) [HCHO2] < [NaCHO2]  
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7) If the pKa of HCHO2 is 3.74 and the pH of an HCHO2/NaCHO2 solution is 3.74, which of the following is TRUE?   show
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show D) 4.49  
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28) Which of the following is TRUE?   show
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29) Define buffer capacity.   show
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30) The highest pH for an effective buffer occurs when the base is how many times as concentrated as the acid?   show
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show C) HClO, pKa = 7.54  
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show E) HClO2, Ka = 1.1 x 10-2  
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show C) adding 0.050 moles of HCl  
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34) A 1.0 L buffer solution is 0.050 M HC2H3O2 and 0.250 M LiC2H3O2. Which of the following actions will destroy the buffer?   show
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show C) 7.4  
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show B) MgCO3, Ksp = 6.82 × 10-6  
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show B) FeS  
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show A) CaCO3 and MgCO3  
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68) Which of the following compounds solubility will not be affected by a low pH in solution?   show
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79) Which of the following compounds will have the highest molar solubility in pure water?   show
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The Ka of hydrazoic acid is 1.9 × 10-5.   show
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The Ka of chloroacetic acid is 1.36 × 10-3.   show
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In which of the following solutions would solid PbBr2 be expected to be the least soluble at 25°C?   show
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show B) 1.6 × 10- 2 M  
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41) What is the molar solubility of AgCl in 0. 10 M NaCN if the colorless complex ion Ag(CN)2- forms? Ksp for AgCl is 1.8 × 10-10 and Kf for Ag(CN)2- is 1.0 × 1021.   show
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show A) The equivalence point is where the amount of acid equals the amount of base during any acid-base titration.  
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show D) pH will be equal to 7 at the equivalence point.  
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38) When titrating a weak monoprotic acid with NaOH at 25°C, the   show
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39) When titrating a monoprotic strong acid with a weak base at 25°C, the   show
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40) Identify the most common indicator.   show
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41) Identify the indicator that can be used at the lowest pH.   show
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show B) thymol blue  
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43) Identify the indicator that can be used at the highest pH.   show
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86) Give the equation for an unsaturated solution in comparing Q with Ksp.   show
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show C) Q = Ksp  
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88) Give the equation for a supersaturated solution in comparing Q with Ksp.   show
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show C) Silver chloride will precipitate out of solution, leaving a saturated AgCl solution.  
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90) A solution containing CaCl2 is mixed with a solution of Li2C2O4 to form a solution that is 2.1 × 10-5 M in calcium ion and 4.75 × 10-5 M in oxalate ion. What will happen once these solutions are mixed? Ksp (CaC2O4) = 2.3 × 10-9.   show
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show D) A precipitate will form since Q > Ksp for calcium oxalate.  
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94) Identify the compound that is acid-insoluble.   show
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95) Identify the compound that is base-insoluble.   show
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96) A sample contains Ba3(PO4)2, CdS, AgCl, NH4Cl, and ZnS. Identify the precipitate after the addition of 6 M HCl.   show
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97) A sample contains Ba3(PO4)2, CdS, AgCl, NH4Cl, and ZnS. Identify the precipitate after the addition of 6 M HCl, then H2S and 0.2 M HCl.   show
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show E) ZnS  
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99) A sample contains Ba3(PO4)2, CdS, AgCl, NH4Cl, and ZnS. Identify the precipitate after the addition of 6 M HCl; H2S and 0.2 M HCl; OH- to a pH of 8; and (NH4)2HPO4 with NH3.   show
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100) A sample contains Ba3(PO4)2, CdS, AgCl, NH4Cl, and ZnS. Identify the soluble ions   show
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show D) Lewis base  
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show A) soluble at low pH, insoluble in pH-neutral solution, and soluble at high pH  
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103) Gives what happens at low pH for aluminum hydroxide.   show
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show C) Al(OH)3 precipitates  
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show B) Al(H2O)2(OH)4- dissolves  
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show B) 1.9 x 10-26 M  
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107) A solution contains 3.8 × 10-2 M in Al3+ and 0.29 M in NaF. If the Kf for AlF63- is 7 × 1019, how much aluminum ion remains at equilibrium?   show
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show C) 0.1 M CaBr2  
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show 5) pH = pKa2  
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show 1)pH = 7  
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C) half-way to equivalence point of a weak acid/strong base titration   show
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D) equivalence point of a weak base/strong acid titration   show
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show 3)pH > 7  
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40) What is the molar solubility of AgCl in 0. 30 M NH3? Ksp for AgCl is 1.8 × 10-10 and Kf for Ag(NH3)2+ is 1.   show
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41) What is the molar solubility of AgCl in 0. 10 M NaCN if the colorless complex ion Ag(CN)2- forms? Ksp for AgCl is 1.8 × 10-10 and Kf for Ag(CN)2- is 1.0 × 1021.   show
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show D) 6.8 × 10-2 M  
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43) A solution of NaF is added dropwise to a solution that is 0.0144 M in Ba2+. When the concentration of F- exceeds __________ M, BaF2 will precipitate. Neglect volume changes. For BaF2, Ksp = 1.7 × 10-6.   show
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