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P Chem

Quiz yourself by thinking what should be in each of the black spaces below before clicking on it to display the answer.
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Term
Definition
thermodynamics   study of transformation of energy  
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system   the quantity of matter when we can draw a boundary  
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surroundings   region outside system we make measurements  
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open system   matter and energy CAN be transferred through boundry between system and surroundings  
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closed system   matter CANNOT be transferred through boundry. Energy CAN be transferred.  
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isolated system   closed system that has no mechanical/thermal contact with surroundings CANNOT transfer matter or energy  
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work   done to achieve motion against an opposing force:Raise weight. when a force acts upon an object to cause displacement of an object. eg. Pushing shoprite cart.  
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energy   capacity to do work  
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heat   energy transferred due to temp. differences ONLY  
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diathermic   boundries that DO permit transfer of energy as heat  
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adiabatic   boundries that do NOT permit transfer of energy as heat  
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exothermic   releases energy as heat into suroundings. combustion increase TEMP  
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endothermic   energy is absorbed by sustem from surroundings as heat  
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thermal motion   disorderly molecular motion in surroundings.  
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internal energy   total energy of system state function deyltaU  
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state function   value depends only on current state of system independent of path  
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first law of thermodynamics   internal energy of an isolated system is constant  
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expansion work   work arising from change in volume  
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nonexpansion work/ additional work   work arising from no change in volume  
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free expansion   expansion against zero opposing force  
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indicator diagram   graph used to show expansion of work  
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reversible change   change that can be reversed by an infinitesimal ,small modification of a variable.  
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calorimetry   study of heat transfer during physical and chemical process.  
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calorimeter   device used to measure energy energy transferred as heat  
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adiabatic bomb calorimeter   measures internal energy when q=0  
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calorimeter constant   c  
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heat capacity   slope tangent to curve at any temp  
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molar heat capacity   Cvm=Cv/n  
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specific heat capacity   Cv/mass  
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enthalpy   u+pV  
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isobaric calorimieter   constant pressure  
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adiabatic flame calorimeter   constant volume  
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differential scanning calorimeter   measure H  
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thermochemistry   study of energy transferred as heat in chem rxn  
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std enthalpy   change in enthalpy when the inital and fianl substances in std state  
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std state   1 bar  
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std enthalpy of transition   change in physical state  
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hfus   s to l  
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hvap   l to g  
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lattice enthalpy   change in std molar enthalpy  
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born haber cycle   solves for lattice enthlpy  
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thermochemical equation   combo of chem eq and corresponding change in std enthalpy  
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std reaction enthalpy   sum of H prod - Sum of Hreac  
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std enthalpy combustion   complete oxidation of organic compound to co2 gas and liquid h2o is contains CHON  
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hess law   enthalpy of an overall rxn is the sum of std enthalpies of individual rxns into which a rxn maybe divided.  
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std enthalpy of form   std rxn enthalpy for formation of compound from its elements in ref states.  
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reference state   most stable state 1 bar  
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stochimetric numbers   vj Hprod-Hreac  
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kirchoff Law   equates emission and absorption in heated objects  
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path functions   depend on path between 2 states  
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exact differential   small quanitity when integrated gives a result that is independent of path between initial and final state.  
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inexact differential   small quantity when integrated gives a result that depends on path between initial and final states.  
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internal pressure   internal energy of system changes when it expands or contracts at constant temp  
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expansion coeff   fractional change in volume when temp increases  
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isothermal compressibility   fractional change in volume when pressure increases  
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isenthalpic   constant enthalpy  
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isothermal joule thomson coeff   slope of graph p vs t  
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inversion temp   critical temp when non ideal gas is expanding at constant enthalpy temp is decreasing.  
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