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CHEMFINALGT11/12

Quiz yourself by thinking what should be in each of the black spaces below before clicking on it to display the answer.
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Question
Answer
Solution   homogeneous mixture of 2+ substances in a single physical state  
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solute   The substance that is dissolved in a solution  
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solvent   It is the substance in which the solute is dissolved.  
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Miscible   soluble, able to be mixed to form a solution  
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Immiscible   the property where two substances are not capable of combining to form a homogeneous mixture  
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Solubility   the ability of one substance to dissolve in another  
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Insoluble   incapable of dissolving in a solvent  
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Solvation    
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Unsaturated   When referring to solutions, being able to dissolve more solute. When referring to organic compounds, containing double or triple carbon-carbon bonds  
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Saturated   A substance in which the atoms are linked by single bonds  
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Supersaturated   the condition in which a liquid has been cooled to a temperature below that at which crystallization normally would occur, without the solid resulting  
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Factors affecting solubility   nature of solute and solvent, temperature, pressure  
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factors affecting rate of solvation   surface area, stirring, temperature  
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concentration   measure of how much solute is dissolved in a specific amount of solvent or solution  
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% by mass=   mass of solute/ mass of solution x100  
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%by volume=   volume component/total moles solution x100  
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molarity   moles of solute/liters of solution  
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mole fraction=   moles of component/ total moles solution  
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molality   moles of solute/ kg of solvent  
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dilution   M1V1=M2V2 (M is molarity here)  
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Colligative properties   depends on concentration of particles in a solution, not upon identity of those particles  
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Freezing Point depression   the phenomenon that occurs when the freezing point of a liquid (a solvent) is lowered by adding another compound to it, such that the solution has a lower freezing point than the pure solvent  
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Boiling Point elevation    
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Vapor Pressure reduction    
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Increased Osmotic Pressure    
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Colloids    
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Suspension    
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Chemical Kinetics   -the area concerned with speed at which reactoins occur -reaction rate is the change in concentration of reactants and rpoducts in a certain amount of time  
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Collision theory   reaction rate depends on the collision between reacting particles  
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Successful collision occur when particles   -collide with each other -have correct orientation -have enough kinetic energy to break bonds  
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activation energy   energy required for a reaction ot occur; depends on reactants  
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low Ea= ____ reaction rate   fast  
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Energy diagram   shows the energy changes that occur throughout a chemical reaction; describes the reaction pathway (mechanism), need to know how to label: reactant energy level, product energy level, activation energy, net energy change  
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5 factors that affet rate of reaction   -nature of reactants -temperature -concentration -surface area -catalysts  
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reversible reactions   A+B-> C+D (forward C+D-> A+B (reverse)  
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Equilibrium   rates are = while concentrations are not rates determined by concentrations and activation energy  
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Homogenous equilibria   all reactions and products are in the same state  
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heterogeneous equilibria   equilibrium conditions for reactants thatinvolve substances in more than 1 state  
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Calculating equilibrium constant   1. Balance equation 2. Write equilibrium expression 3. Substitute the equilibrium concentrations 4. Do the math K>1 favors right, K<1 favors left, K= 1 equal  
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LeChatelier's Principle   -if a stress is applied to a system at equilibriu, the equilibrium will shift to reduce stress  
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3 types of stress   -change in concentration -change in pressure: changes volume, system moves depending on moles of gas -change in temp: treat heat as a reactant/product, chagne sin temp like changing conc of heat  
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Reaction Quotient (Q)   the proportion of products/reactants at a specific point in time  
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Naming of Acids and Bases   -Bases: namedlike ionic compounds -Acids names depend on ion endings  
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ate=   -ic acid  
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ite=   -ous acid  
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ide   hydro -ic acid  
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titration   analytical method in which a standard solution is used to determine the concentration of unknown solution, based on a neutralization reaction  
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MVn=MVn (Molarity, Volume and Number of H+ (acids) or OH- (bases)    
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Monoprotic   acids that contain one ionizable hydrogen  
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diprotic   acids that contain two ionizable hydrogens  
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triprotic   acids contain three ionizable hydrogens  
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amphoteric substances   can act as either acid or base depending on what they are mixed with  
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Arrhenius   H+ producer OH- producer  
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Bronsted-Lowry   H+ donor H+ acceptor  
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Lewis   electron pair acceptor, electron pair donor  
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When an acid loses an H+ it becomes a conjugate ____   base  
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When it gains an H+ it becomes a conjugate ____   acid  
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pH=   log(H3O+)  
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pOH=   log(OH-)  
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pH+ pOH=   14  
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hydrocarbons   organic compounds made of only carbon and hydrogen - 3 categories: alkanes, alkenes, and alkynes -know how to name alkanes, alkenes, and alkynes  
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