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FURTHER ORGANIC /2

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Answer
1 way to prepare chloroalkane Add phosphurus pentachloride to the ALCOHOL. POCl3 + HCl+ halogenalkane    
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2nd method to prepare chloroalkanes. Way less efficiently coz some DEHYDRATION of alcohol to propene occurs. Add conc sulfuric acid to mixture of propan-ol- and KCl. H2S04 protonates alcohol & HCl from KCl.    
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1 way of preparing bromoalkanes? 50% of aulphuric Acid. slowly added with cooling to the alcohol. MIXTURE added to solid KBr & HEATED.    
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Bromoalkane BP(59degrees) more volatile than alcohol BP 82. So DISTILLS off CONDENSED ,COLLECTED.    
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1 way to prepare iodoalkanes? can't use 50% of sulphuric acid - will oxidise HI. Alcohol warmed with mixture DAMP RED PHOSPORUS and IODINE. IODINE react with PHOSPHORUS - FORM PHOSPHURUS TRIIODIDE. = REACTS WITH ALCOHOL to form IODOALKANE.    
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Concentrated sulphurix acid would? oxidise HALOGENOALKANE.    
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What is substitution? reaction when atom or group replaced by other atom of group.    
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Examples of nucleophiles for nucleophillic substitution? -OH , -CN , -NH2    
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in nucleophilic substitution? bond made to CARBON using lone pair of electrons and halide Ion RELEASED.    
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what is a necleophile? A species with lone pair of elctrons that is used to form covalent bond with pos atom in another molecule.    
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Reaction with aqueous alkali? reagent :sodium or K hydroxide. Conditions: heat under reflux in aqueow solution. Product : propan-1-ol reaction type:-nucleophilic substitution(hydrolysis)    
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How is nucleophilic substitution sometimes carried out with OH ? why? with halogenalkane dissolved in alcohol. alkali dissolved in water . organic compound not water soluable - little contact between it and OH ions.    
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