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biochem carbohydrates

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Question
Answer
dihydroxyacetone   monosaccharide ketotriose  
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d-glyceraldehyde   monosaccharide aldotriose  
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most common monosaccharide   hexoses  
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d-glucose   aldohexose  
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d-fructose   ketohexose  
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d-ribose and 2-deoxy-d-ribose   aldopentose  
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D and L are defined in referece to   the configuration of the chiral carbon farthest from the carbonyl group in glyceraldehyde  
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in nature most monosaccharides are D OR L   d  
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d-mannose   aldohexose  
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d-galactose   aldohexose  
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what determins D or L   last chiral center(-OH) fartest away from carboxyl group. where the OH is for us  
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Rib   Ribose pentose aldose  
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Glc   Glucose hexose aldose  
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Man   Mannose hexose aldose  
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Gal   Galactose hexose aldose  
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Glyceraldehyde   triose aldose  
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dhydroxyacetone   triose ketose  
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Fru   Fructose hexose Ketose  
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sugar that differ only in their configuration at one chiral cneter   epimer  
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most sugar form rings by joing a   carbony and alcohol group to to get hemiacetals hemiketals  
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pyranoses   6 member ring with different conformation 2 chair and boat  
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furanoses   5 member ring  
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anomers   monosaccharides differeing only in their conFIGURation at the hemiacetal/hemiketal carbon alpha beta  
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mutarotation   interconversion of anomers in aqueious solution at equilibrium (some linear)  
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hexoses derivative   diff structure differ groups attacted and in different placesn-acetyl-b-d-glucosamine  
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haworth perspectives   a-d glucopyroanose b-d-glucopyranose a-d and b-d fructofuranose  
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howorth perspective   show stereochemistry of ring forms of monosaccharides there are different conformation of d-pyranoses adn d-furanoses alpha and beta not different configurations  
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what two polysaccaride are for storage   starch and glycogen  
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in plants and anomeric carbon is in the alapha configurationo   starch  
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unbranched glucose polymer with alapha 1->4 linkage   amylose  
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alpha 1->4 linkage branched every 24-30 branched at alpha 1-6   amylopectin  
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alpha1 ->4 linkage branched 8-12 using alpha 1-6   glycogen  
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most abundant polysaccharide in nature   cellulose  
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an unbranched polymer of glucose monomers the anomeric carbon is in the beta configuration   cellulose  
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unbranched polymer of n-acetylglucosamine   chitin  
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2nd most abundant polysacch   chitin  
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two advantage of storing as polymers rather than monomers   osmolarity and conc. gradient or thermodynamic the insoluable polymer glycogen  
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advantage of branching   quicker degradation by enzymes that attack only non-reducing sugars  
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two heteropolymers   peptidoglycans and glycosaminoglycans  
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hyloranate, chnodron, keratin, heprin are what type of structural heterpolymer   glycosaminolgycans  
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the two heteropolymer have what in common   reapeating diaccharides  
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which polymer has x-links   peptidoglycans  
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found in bateria cell wal   peptidoglycans  
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foudn in fungi cell wall   chitin  
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homo and heter or storage, structural or both   homo both and heter just struct  
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what two polysacc are both polymers of glucose monomers   cellulose and amylose cellulose has beta and amylose has alpha though  
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what are the four types of glycoconjugates   proteoglycans, glycoproteins, glycolipids and lipopolysaccharides  
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what glycoconjugate is made up of glycosaminoglycans and protein   proteoglycans  
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what glycoconjugate is made up of protein and carbohydrate   gycoproteins  
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what glycoconjugate is made up of membrance lipid and oligosaccharide   glycolipids  
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what two places can you find a proteoglycan   cell surface or in ECM  
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structure componet of proteoglycans   one or more glycosaminoglycan chains covalently bound to a core protein  
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what can absorb/release large amounts of water and function as shock absorbers (repeating units and core protein   proteoglycan aggregates *absorb water*  
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glycoproteins are made up of   one or more oligosaccharides  
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which glycoconjagate's carbohydrate components are smaller and more sturctually diverse than proteoglycans   gycoproteins  
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what have many large carbonhydrate components and not a variety   proteoglycans  
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where can you find a glycoprotein   on cell surface or secreted into ECM  
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hormones and lg's are which glycoconjugate   glycoproteins  
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what glycoconjugate is made of a lipid convalently bound to oligosaccharides   glycolipids structure  
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which glycoconjugate is often the binding site for proteins such as blood group determinants   glycolipids  
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dominant surgace feature of gram-negative bacteria   lipopolysaccharides lipid with sugar  
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prime target of anitbodies is which glycoconjugate   lipopolysaccharides  
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lipid in CM convalently bond to oligsaccharide on the outer surface to mark cell   glycolipid  
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how are blood group determinants different   the difference of one monosaccaride. you either have the enzyme or not to have ability to add monosacchride  
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lectins are _____ not carbohydrate   proteins  
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proteins that specifically and strongly bind carbohydrates are   lectins  
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what serves a wide variety of cell-cell recognition and adhesion processes   lectins  
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selectins are a type of lectin found on a cell that will recognize a oligosacharide of another cell   (blank)  
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what part of the cell does a virus bacteria or toxin recognize and attack   the oligosaccaride portion of the glycolipid or glycoprotein toxin attack glycolipid  
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