click below
click below
Normal Size Small Size show me how
Proton NMR shifts
The proton chemical shifts of a selection of funtional groups
| Question | Answer |
|---|---|
| Cyclopropane C3H6 | 0.2 |
| Primary R-CH3 | 0.9 |
| Secondary R2-CH2 | 1.3 |
| Tertiary R3-C-H | 1.5 |
| Vinylic C=C-H | 4.6-5.9 |
| Acetylenic triple bond,CC-H | 2-3 |
| Aromatic Ar-H | 6-8.5 |
| Benzylic Ar-C-H | 2.2-3 |
| Allylic C=C-CH3 | 1.7 |
| Fluorides H-C-F | 4-4.5 |
| Chlorides H-C-Cl | 3-4 |
| Bromides H-C-Br | 2.5-4 |
| Iodides H-C-I | 2-4 |
| Alcohols H-C-OH | 3.4-4 |
| Ethers H-C-OR | 3.3-4 |
| Esters RCOO-C-H | 3.7-4.1 |
| Esters H-C-COOR | 2-2.2 |
| Acids H-C-COOH | 2-2.6 |
| Carbonyl Compounds H-C-C=O | 2-2.7 |
| Aldehydic R-(H-)C=O | 9-10 |
| Hydroxylic R-C-OH | 1-5.5 |
| Phenolic Ar-OH | 4-12 |
| Enolic C=C-OH | 15-17 |
| Carboxylic RCOOH | 10.5-12 |
| Amino RNH2 | 1-5 |