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PRACTICE CHEM
actual
| Question | Answer |
|---|---|
| CH4 | only london dispersion force |
| what's the predominant intermolecular force in CBr4 | london dispersion force |
| what force is responsible for the fact that ice is less dense than liquid water? | hydrogen bonding |
| how high a liquid will rise up a narrow tube as a result of capillary action depends on | the magnitudes of cohesive forces in the liquid & adhesive forces b/w the liquid & the tube, and gravity |
| London dispersion forces tend to increase in strength | with increasing molecular weight |
| the initial discovery of liquid crystal resulted from studies on | cholestryl benzoate |
| basis of the VSEPR model of molecular bonding is | electron domains in the valence shell of an atom will arrange themselves to minimize repulsions |
| the O-C-O bond angle in the CO3-2 ion is | 120 |
| the central Xe atom in the XeF4 molecule has | 2 unbonded electron pairs & 4 bonded electron pairs in its valence shell |
| the electron domain geo & molecular geo will always be the same if | there are no lone pairs in the central atom |
| molecular geometry of BeCl2 is | linear & nonpolar |
| NCL3 is | polar bc it has nonbonding pairs |
| molecular geometry of CHF3 | tetrahedral & polar |
| molecular geometry of BCl3 | trigonal planar, & nonpolar |
| molecular geometry of SF6 | octahedral & nonpolar |
| according to the valence bond theory, which orbitals overlap in the formation of the bond in HBr? | 1s on H & 4p on Br |
| Seesaw shape is | TeCl4 |
| the combination of 2 atomic orbitals results in the formation of | 2 molecular orbitals |
| when 3 atomic orbitals are mixed to form hybrid orbitals, how many hybrid orbitals are formed? | 3 |
| in a polyatomic molecule, "localized" bonding electrons are associated with | 2 particular atoms |
| delocalized b.electrons are associated with | all of the atoms in the molecule |
| SO2 SO3 O3 NO3- | delocalized bonding |
| the N-N bond in HNNH consists of | one sigma bond & one pi bond |
| the hybridization of the terminal carbons in the H2C=C=CH2 molecule is | sp2 |
| 2 electron domains is what hybridization? | sp |
| structural changes around a double bond in the ________ portion of the rhodopsin molecule trigger the the chemical reactions that result in vision | RETINAL |
| for a molecule with the formula AB3, molecular shape is | trigonal planar, trigonal pyramidal, or T-shaped |
| molecular geometry of SF2 molecule is | bent (2 bonding & nonbonding) |
| angles between sp2 orbitals are | 120 |
| what is the molecular geometry of a molecule that has 3 bonding & non bonding domains? | t-shaped |
| what are the 3 bond angles in the trigonal bipyramidal structure? | 90, 120, 180 |
| the 1s hydrogen orbital overlaps with the ____ iodine orbital in HI | 5p |
| a covalent bond in which overlap regions lie above & below an internuclear axis is | pi bond |
| molecular orbital theory the stability of a covalent body is related to its | bond order |
| H2S | odor of rotting eggs |
| 130 mm HG or torr | systolic pressure is 1st measurement or max pressure when heart is pumping 120/80 |
| what statement about atmospheric pressure is false | with an increase in altitude, atm increases as well. NO. it DECREASES. |
| removal of ____ from the natural gas both purifies the natural gas & serves as an alternative method of production of an industrially imp. chemical element | H2S |
| square root of (3*8.314*T)/ molecular mass X 10-3 | root mean square speed |
| effuse R1/R2 = sq. root of R2/R1 | square root of heavier over lighter |
| a real gas wil behave most like an ideal gas under conditions of | high temperature & low pressure |
| noble gas with largest deviations from the ideal gas behavior | XENON |
| the height of the mercury column at 1 atm is | 760 mm |
| reaction of 50 ml N2 & 150 ml H2 produces | 50 + (150/3 mols) = 100 ml |
| rxn of 25 & 75 ml | 25 + (75/3) = 50 ml |
| P1/Ptotal = N1/Ntotal | partial pressure |
| the van der waals eq. corrects the ideal gas law for the finite volume & | attractive forces of gas molecules |