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Vocabulary Unit 2
Periodic Trends
| Term | Definition |
|---|---|
| Coulomb's Law | =The force of attraction between charged particles depends on the amount of charge and the distance between them. Greater charge creates stronger attraction and greater distance creates weaker attraction. |
| Electron Shielding | The blocking effect of inner electrons that reduces the attraction between the nucleus and the valence electrons. |
| Effective Nuclear Charge (Zeff)The net positive charge felt by an electron after accounting for electron shielding. A greater effective nuclear charge pulls electrons closer to the nucleus. | The net positive charge felt by an electron after accounting for electron shielding. A greater effective nuclear charge pulls electrons closer to the nucleus. |
| Ionization EnergyThe energy required to remove an electron from a gaseous atom or ion. | The energy required to remove an electron from a gaseous atom or ion. |
| First Ionization EnergyThe energy required to remove the first electron from a neutral gaseous atom. | The energy required to remove the first electron from a neutral gaseous atom. |
| Successive Ionization Energy | The energy required to remove additional electrons one at a time after the first electron has been removed. A large increase occurs when a core electron must be removed. |
| Photoelectron Spectroscopy (PES) A method that uses light to remove electrons from atoms and measure their binding energies to determine electron arrangement. | A method that uses light to remove electrons from atoms and measure their binding energies to determine electron arrangement. |
| Binding Energy | The energy required to remove an electron from an atom. Electrons held more strongly by the nucleus have greater binding energy. |
| Periodicity | The repeating pattern of element properties that occurs across the periodic table. |
| Ionic Configuration | The arrangement of electrons in an ion after an atom gains or loses electrons. |
| Isoelectronic Series | A group of atoms or ions that have the same number of electrons but different numbers of protons. More protons results in a stronger attraction and smaller radius. |
| Atomic Radius | The size of an atom based on the distance between its nucleus and outer electron cloud. Atomic radius decreases from left to right across a period and increases down a group. |
| Ionic Radius | The size of an ion. Cations are smaller than their neutral atoms while anions are larger than their neutral atoms. |
| Electronegativity | The ability of an atom to attract shared electrons in a chemical bond. Electronegativity increases from left to right across a period and decreases down a group. |
| Electron Affinity | The energy change that occurs when a neutral gaseous atom gains an electron. |
| Anion | A negatively charged ion formed when an atom gains electrons. |
| Cation | A positively charged ion formed when an atom loses electrons. |
| Core Electrons | Electrons in the inner energy levels that shield valence electrons from the full attraction of the nucleus. |
| Law of Conservation of Energy | Energy cannot be created or destroyed. It can only be transferred or changed from one form to another. |
| Law of Conservation of Mass | Matter cannot be created or destroyed during a chemical reaction. The total mass of the reactants is the same as the total mass of the products. |
| Ground State | The lowest energy arrangement of electrons in an atom. |
| Ionization | The process in which an atom gains or loses electrons and becomes an ion. |
| Octet Rule | The tendency of atoms to gain lose or share electrons to obtain eight valence electrons and become more stable. |