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chemistry

QuestionAnswer
What is the amu (mass) of a proton? 1 amu
What is the amu (mass) of a electron 0 amu
What is the amu (mass) of a neutron 1 amu
What is the charge of a protron? +1 *positive
What is the charge of a neutron? 0 *neutron=neutral
What is the charge of a electron? -1 *negative*
where is a protron located? in the nucleus
where is a neutron located? in the nucleus
where is an electron located? in orbitals outside of the nucleus
What is an atomic number? the number of protons in the nucleus of an atom
What number uniquely identifies an element in the periodic table, increasing across a period? An atomic number
What did Charles Darwin believe about the atom? It was a solid, indivisble, indestructible, hard sphere
What did Thomson discover about the atom? Negative electrons, and created the plum pudding model,
How did Thomson discover negative electrons and the plum pudding model By using a cathode ray tube that showed the atom being deflected towards the positive ray, showing there was negatively charged particles inside the atom
What did James Rutherford prove about the atom? The atom is mostly empty space, with a dense, positively charged nucleus.
What process did James Rutherford use to discover the atoms positively charged nucleus? The Gold Foil Experiment, where he bombarded thin gold foil with positive alpha particles, most passed straight through, but a few deflected at sharp angles.
What did the Bohr model of the atom represent? Electrons travel around the nucleus in fixed, concentric, circular tracks called shells/energy levels.
What is the Wave-Mechanical Model The modern model of the atom, that states that electrons reside in orbitals, which are defined as the most probable locations for finding an electron.
What is an orbital the most probable locations for finding an electron.
What is the net nuclear charge of an atom? Always equal to the number of protons (atomic number) Ex: carbon (6 protons) has a nuclear charge of +6 This is because only the protons and neutrons are in the nucleus, but neutrons have a charge of 0.
What is an Isotope? Atoms of the same element containing the same number of protons but a different number of neutrons. They have the same atomic number but different mass numbers.
What is an average atomic mass? The weighted average atomic mass of the naturally occurring isotopes of an element
How do you calculate the average atomic mass of an element? ((mass(of isotope 1) )x(abundance(of isotope 1) /100)) +( (mass(of isotope 2) )x(abundance(of isotope 2) /100) )
What is the ground state of an electron? When electrons occupy the lowest possible principal energy levels as listed on the periodic table ex: Fluorine=2-7
What is an excited state of an electron? when valence or inner electrons absorb specific amounts of energy and temporarily jump up to a higher, unoccupied or partially filled energy shells ex: Fluorine shifting from 2-7 to 2-6-1
How can you identify if you are looking at an excited state of an electron or not? If there is an electron in an energy shell without the previous shell being filled.
How is a Bright-Line Spectra produced? When electrons fall back from excited states to ground states, they emit photons (forms of light energy). The emitted energy matches the exact difference between the two shell levels, with every element having an unique configuration.
What is the modern Periodic Table structured in order of Increasing atomic number.
What do Periods indicate on the Periodic Table The total number of occupied shells. Periods= horizontal rows
What do Groups indicate on the Periodic Table elements with identical numbers of valence electrons
Why are elements in the same group so alike? They have the same number of valence electrons
What do valence electrons indicate? Unique chemical properties and reactivity traits of an element
What is the change in atomic radius across a period It decreases, due to the increasing nuclear charge (more protons) drawing the electron shells closer
What is the change in atomic radius down a group It increases due to the addition of new electron shells
What is the change in electronegativity down a group It decreases down a group
What is the change in electronegativity across a period It increases
What element has the highest electronegativity Fluorine(F) with a value of 4.0
What is electronegativity? A metric of an atom's relative attraction for electrons within a chemical bond.
What is the change in first ionization energy down a group Decreases down a group
What is the change in first ionization across a period Increases
What is first Ionization Energy? The clean thermal threshold required to strip away the most loosely bound valence electrons from a gaseous atom.
Where are the metals on the periodic table? Situated to the left of the bold staircase line (except Hydrogen)
What are characteristics of a metal? Low ionization energy, low electronegativity, high thermal/electrical conductivity, lustrous sheen, and high malleability and ductility.
Where are the non-metals on the periodic table? Positioned to the right of the bold staircase line
What are characteristics of a non metal? High ionization energy and electronegativity. Generally brittle solids or gases at STP and function as poor conductors.
What are the elements in Group 18 classified as? Nobel Gases
What are the characteristics of a Nobel Gas? highly unreactive due to a stable octet (8 valence electrons, 2 for Helium)
What are Metalloids (Semimetals)? All of the elements bordering the staircase line that display a blend of metallic and nonmetallic characteristics.
Name the 6 Metalloids Boron, Sillicon, Geranium, Astatine, Antimony, Tellerium. B, Si, Ge, As, Sb, Te BAS TESI GESB
What are the transition Metals? are elements in groups 3 to 12 of the periodic table, characterized by partially filled d orbitals and the ability to form multiple oxidation states.
What are unique characteristics of transition metals form colored compounds, have varied oxidation states, high melting and boiling points, good conducters of heat and electricity
What type of ions does metals form? Positive ions, metals LOSE electrons
What type of ions does nonmetals form? Negative ions, non-metals GAIN electrons
Are metal atoms or metal ions bigger? metal atoms are bigger than metallic ions because the outer valence shell is completely shred.
Are non metal atoms or non metal ions bigger? non metal ions are bigger than non metal atoms because incoming electrons increase intra-shell repulsion, expanding the cloud
What is the Law of Conservation? Every closed chemical reaction must perfectly conserve mass, charge, and energy. The net mass of the starting reactants must precisely equal the net mass of the final products.
What must every closed chemical reaction perfectly conserve? Mass, charge, and energy.
What is an empirical formula? The most structurally reduced, simplest whole number ratio of atoms present within a compound ex: C5H7 CH2
What is a molecular formula? The actual chemical composition stating the total count of atoms in a molecule ex: C3H6
How do you find the molecular formula from molecular mass and empirical mass? divide the true molecular mass by the calculated empirical formula mass to find a whole-number scalar multiplier, then scale all subscripts
How do you name a binary ionic compound? state the metal name first, followed by the non-metal ending in "-ide" ex: NaCl = Sodium Chloride
What do you do if naming a binary ionic compound with transition metals? If the metal can showcase multiple positive oxidation states (groups 3-12), use a roman numeral to explicitly indicate it's positive charge ex: FeCl2 = iron (II) chloride & FeCl3= iron (III) chloride
What is a polyatomic ion? compounds featuring three or more elements containing a polyatomic grouping. Identify these structural configurations on Table E.
How do you find the GFM (gram formula mass) of a compound? Add all of the atomic weights of all atoms in a chemical formula, making sure to multiply each atomic weight by its subscript coefficient.
What is percent composition by mass? (mass of part/ mass of whole) x 100
how do you calculate the amount of moles of an element mass (given)/ gfm of the element
What happens in terms of energy when you break a chemical bond? Energy is absorbed
What happens in terms of energy when you form a chemical bond? energy is released.
is breaking a bond endothermic or exothermic endothermic; the system absorbs heat
is forming a bond endothermic or exothermic exothermic; the system expels heat to stabalize
why do atoms bond? to achieve a stable valence octet matching a Nobel gas configuration
What is an ionic bond? when a metal bonds with a non metal, driven by electrostatic attractions between positive cations and negative anions. Characterized by HIGH electronegativy differences. Only conduct electricity in water
What happens with electrons in ionic bonds Electrons are transferred
How do ionic compounds conduct electricity? because Solid ionic compounds lock ions in a rigid crystal lattice and do not conduct electricity, ions only conduct electricity when they are melted into the liquid phase or dissolved into water to make an aqueous solution. This allows mobile ions to break away and freely conduct electrical current.
What are covalent bonds? When two non-metal atoms bond
What happens in terms of electrons in covalent bonds pairs of valence electrons are shared
Are ionic compounds polar or nonpolar? ionic bonds are the most polar bonds.
What are non polar covalent bonds? When electrons are shared perfectly equally between identical atoms with an electronegativity difference of zero.
What are polar covalent bonds? electrons are shared unequally due to mismatched electronegativitys. this aquires a partially negative charge
what are metallic bonds formed within pure metal matrices or alloys ex: Fe
What are characteristics of metallic bonds? rigid arrays of positive metal cores surrounded by a continuous "sea of mobile valence electrons"'. The constant electron mobility allows metals to conduct electricity in the solid phase.
What is the acronym for Bond Energy Dynamics? BARF break absorb, release form when bonds break; they absorb when bonds form; they release
what is the acronym for molecular polarity SNAP symmetrical nonpolar; asymmetrical polar if a molecule is structurally symmetrical, it is nonpolar if a molecule is structurally asymmetrical, it is polar
What is molecular polarity The symmetry of the overall molecule, not just individual bonds.
What are symmetrical molecules? They display a perfectly balanced, uniform distribution of electrical charge and are always Nonpolar. a molecule can contain polar bonds but be highly symmetrical, making them nonpolar molecules ex: CH4, CO2
What are asymmetrical molecules? they display an uneven or skewed distribution of charge and are always Polar. Have lone pair
What are intermolecular forces? weak attractions occuring between independent molecules that dictate macroscopic (big) properties.
What do strong intermolecular forces cause? elevated boiling points, elevated melting points, and depressed vapor pressures.
What is hydrogen bonding? an unusually powerful IMF that occurs when Hydrogen is directly bonded to a small, highly electronegative nonmetal atom: Fluorine, oxygen, or nitrogen (FON) Causes unusually high boiling points
What is vapor pressure? The upward force exerted by a liquid converting to gas. When the vapor pressure of a liquid equals the surrounding atmospheric pressure, the liquid boils.
What is the relationship between IMF and vapor pressure? Stronger IMF= lower vapor pressure at a given temperature
Where can you find vapor pressure in the reference table table H
What is a pure substance? homogenous matter with fixed composition -elements and compounds are both examples
define element an atom that cannot be decomposed by any chemical means
define compound two or more unique elements chemically locked in a fixed ratio; can be broken down chemically
what are allotropes? two or more structural modifications of the same exact element in the same physical phase ex: o2 (g) & o3 (g) carbon as a diamond vs graphite
what are properties of allotropes? they possess distinct crystal or molecular geometries; resulting in completely different physical and chemical properties
what are ions? elements with a charge
what are mixtures? physical blends of two or more substances that are combined in variable ratios
what are homogenous mixtures? mixtures with uniform composition throughout, cannot visibly see the different elements. aqueous solutions ex: NaCl (aq)
what are heterogenous mixtures? non-uniform composition with visible phase boundaries ex:sand and water
Define Filtration seperating insoluble solids from liquids using a filter medium that allows the fluid to pass while retaining the solids.
define distillation is a physical separation technique in chemistry that purifies liquids or separates liquid mixtures based on differences in their boiling points.
define chromatography a technique for the separation of a mixture by passing it in solution or suspension through a medium in which the components move at different rates.
define evaporation Removes a liquid from a solid by heating; used for separating a soluble solid from a liquid
define Decantation Pouring off a liquid after a solid has settled; used after sedimentation
define sedimentation Letting insoluble particles settle to the bottom of a container before separation
define Sublimation Converting a solid directly to vapor and back to solid without passing through the liquid phase
what is the acronym for the idea of how a real gas behaves close enough to an ideal gases PLIGHT pressure low, ideal gas, temperature high
what are characteristics of an ideal gas - gas particles travel in constant, random, straight-line motion - the actual volume of individual gas particles is completely negligible compared to the volume of the space separating them - gas particles exert zero attraction to one another -collisions are elastic; kinetic energy is transferred between particles but no net system energy is lost
what are the two real gases that closest mimic ideal gas behaviors Helium (He) and Hydrogen (H2) due to their minimal mass and weak IMFs
What is Avagadro's Gas Hypothesis? equal volumes of different ideal gases, measured at the same temperature and atmospheric pressure, contain the identical number of gas molecules or particles, regardless of the gas's chemical composition, formula, or mass number.
What is average kinetic energy equal to? temperature
What is potential energy? the tracking in particle spacing. shifts during phase changes
what is it called when atom shifts from a solid to a liquid ? melting point
what is it called when atom shifts from a liquid to a gas ? boiling point
what are melting and boiling and sublimation examples of endothermic reactions
what is it called when atom shifts from a gas to a liquid ? condensing
what is it called when atom shifts from a liquid to a solid ? freezing point
what is it called when atom shifts from a solid to a gas ? sublimation
what is it called when atom shifts from a gas to a solid ? deposition
what are freezing and condensing and deposition examples of exothermic reactions
what are the melting/freezing plateaus called? heat of fusion
what are the boiling/condensing plateaus called? heat of vaporization
what is the melting point of water? 0 degrees Celsius, 32 degrees Fahrenheit
what is the boiling point of water? 100 degrees Celsius, 212 degrees Fahrenheit
What is a solution? a homogenous mixture containing a dissolved solute uniformly dispersed throughout a solvent.
what do aqueous solutions use as a solvent? water
What is Table F used for? to predict if a compound is soluble or insoluble in water
what is solubility? if a compound forms an aqueous phase with mobile ions what
what is insolubilty? if a compound forms a solid precipitate in a double replacement reaction
What is Table G used for? it graphs the mass of solute per exactly 100 grams of water versus temperature.
what is a saturated solution? - when a solution contains the maximum solute possible; any data point falls exactly on the curve
what is an unsaturated solution? - when a solution holds less than the maximum solute possible; any data point falls below the curve
what is a supersaturated solution? when a solution is in an unstable state holding excess solute; any data point falls above the curve
what is thermal behavior with solid lines on Table G(solubility curves) solid lines slope upward because solids generally dissolve better at higher temperatures
what is thermal behavior with gas lines on Table G(solubility curves) gas lines (HCl, NH3, SO2) slope downwards because gases dissolve best under low temps and high pressures
how do you calculate molarity? M= moles of solute/ liters of solution *MAKE SURE THE VOLUME IS IN LITERS
how do you calculate the parts per million (PPM) in a solution ppm= (mass of solute/ total mass of solution) * 1,000,000 * TOTAL MASS OF SOLUTION= the combined mass of solute plus water solvent
what are colligative properties? solution properties that depend on the number of solute particles relative to solvent particles, not on the solute’s chemical identity.
what happens when you add a nonvolatile solute to a solvent it alters physical constants, causing boiling point elevation and freezing point depression.
what determines the magnitude of the effect in terms of colligative properties? the concentration of dissolved particles -ionic solutes that dissociate into multiple ions cause a greater shift tjan covalent solutes that do not dissociate ex: CaCl2 -> Ca+2 +2Cl-1 (3 moles) vs C6H12O2 (1 mole)
What is the Collision Theory? The theory that states that a chemical reaction can only occur if reactant particles undergo effective collisions
What is the two criteria needed for an effective collision? energy & orientation
How do you increase reaction rates in chemical reactions? -raising concentrations -increasing temperatures -increasing surface area of solids - increasing pressure (gases only) -adding catalyst
What is a catalyst? A catalyst is a substance that accelerates a chemical reaction without being consumed, by providing an alternative pathway with lower activation energy.
What is the heat of reaction? The difference between the Potential energy of the products and the potential energy of the reactants
What is an exothermic reaction? a reaction that releases energy - products have less energy than reactants, resulting in a negative heat of reaction --energy is written on the products side
what is an endothermic reaction? a reaction that absorbs energy - products have more energy than reactants, resulting in a positive heat of reaction -energy is written on the reactant side
what is entropy? a measure of the randomness or disorder of a system
what does nature favor in processes in terms of energy and entropy higher entropy, lower energy
how does entropy increase? as matter changes phase; solid -> liquid ->aqueous -> gas
how is equilibrium established in a closed system? the rate of the forward reaction equals the rate of the reverse the concentrations of all reactants and products remain constant
what is Le Chatelier's Principle? When a system at equilibrium is subjected to environmental stress, it will shift in the direction that counteracts the stress
What are concentration shifts in a system in equilibrium? When you add a substance that causes a shift away from that side to consume the excess. Removing a substance causes a shift toward that side
What happens when you raise temperature in a chemical equilibrium reaction? there is a shift away from the heat term
What happens when you lower temperature in a chemical equilibrium reaction? there is a shift toward from the heat term
What happens when you raise pressure in a chemical equilibrium reaction? shifts the equilibrium toward the side featuring the fewest total gas moles
What happens when you decrease pressure in a chemical equilibrium reaction? shifts the equilibrium toward the side featuring the most total gas moles
What happens when you raise pressure in a chemical equilibrium reaction, but gas moles are equal on both sides of the equation the pressure change does not cause a shift
What do all organic compounds have in them? A carbon molecule
What are Hydrocarbons Compounds that contain a carbon and a hydrogen
what are saturated hydrocarbons hydrocarbons that contain exclusively single carbon-carbon bonds -belong to alkanes
what are unsaturated hydrocarbons hydrocarbons that contain at least one multiple carbon-carbon bonds -belong to alkenes, alkynes
what are alkanes? hydrocarbons with a single bond, following the general formula CnH2n+2 -saturated
what are alkenes? hydrocarbons with a double bond, following the general formula CnH2n -unsaturated
what are alkynes? hydrocarbons with a triple bond, following the general formula CnH2n-2 -unsaturated
what are structural isomers? organic compounds that share the identical molecular formula but possess different structural arrangements -completely different physical properties
define substitution the process where one or more atoms are replaced by another atom or group of atoms in a molecule (organic chem)
define addition *organic chems version of synthesis is a type of chemical reaction in which two or more molecules combine to form a single product,
define esterification when an organic acid reacts with an alcohol to produce an ester and a water
define fermentation when a carbohydrate decomposes into an alcohol and carbon dioxide
define saponification a long chain ester reacts with an inorganic base to produce soap and glycerol
define polymerization monomer units linked together into long chains called polymers
What is the definition of redox (or acronym you can use to remember it) LEO goes GER
What does LEO stand for in LEO goes GER Lose electrons oxidize (oxidation) -oxidation state mathmatically increases
What does GER stand for in LEO goes GER Gain electrons reduce (reduction) -oxidation states mathmatically decrease
In redox reactions, the total moles of electrons lost must _____ the total most gained equal
What is the oxidation number of uncombined free elements ex: O2 always zero
In a neutral compound, what must the net sum of oxidation numbers equal zero
In a polyatomic ion, what must the net sum of oxidation numbers equal the net charge of the ion
What occurs at the anode? oxidation
what occurs at the cathode? reduction
what is An Ox & Red Cat anode= oxidation cathode = reduction
in any electrochemical cell, where do electrons travel through the external circuit wire
in any electrochemical cell, where do electrons travel to and from from the anode to the cathode
what type of energy does electrolytic cells convert, and what does it convert it into electrical energy -> chemcial energy
what type of energy does voltaic cells convert, and what does it convert it into chemical - > electrical
which type of cell is spontaneous voltaic
which type of cell requires a battery electrolytic cell
in a voltaic cell, what is the charge of the anode and cathode? anode= negative cathode= positive
in a electrolytic cell, what is the charge of the anode and cathode anode=positive cathode = negative
in a voltaic cell, what does the salt bridge do? allows the migration of ions, completes the circuit and maintains neutrality
in a electrolytic cell, what is required an external power source
what is an electrolytic cell used for to plate metal onto objects
in an electrolytic cell, what is the cathode always the object to be plated
What are Arrhenius Acids? compounds that dissolve in aqueous solutions to yield hydronium ions (hydrogen ions) as the only positive ions in the solution
What are Arrhenius Bases? compounds that dissolve in aqueous solutions to yield hydroxide ions (OH-) as the only negative ions in the solution
What is the Bronsted-Lowry theory? Acids act as proton (H+) donors, while bases act as proton (H+) acceptors
what do acids, bases, and salts do when they dissolve in water they all release mobile ions, creating electrolytes that conduct electricity. conductivity increases with ion concentration.
what are salts? ionic compounds
what does the pH scale measure? hydronium ion concentration
what does a pH of 7 indicate a neutral substance
what does a pH below 7 indicate an acidic substance
what does a pH above 7 indicate a basic substance
what does every single step of 1 pH unit represent? a 10-fold change in the concentration of hydronium ions
what is a neutralization reaction? when a acid bonds with a base producing a water and a salt
when a acid bonds with a base, what is produced? a water and a salt
what is a titration? a laboratory method used to find the concentration of an unknown solution by reacting it with a solution of known concentration.
what are indicators things that change color at specific pH ranges
what is a nuclear reaction? is a process in which the nucleus of an atom changes, resulting in the formation of new elements or isotopes, often accompanied by the release or absorption of energy.
how is a radioactive nuclide unstable? if it possesses an unfavorable neutron-to-proton ration
how does a radioactive nuclide reach stability? By undergoing spontaneous decay, emitting ionizing radiation
define natural transmutation In natural transmutation, unstable atoms (called radioactive isotopes) decay over time, releasing particles or energy. -spontaneous -represented with ONE reactant on the left side
define artificial transmutation when scientists forcefully convert a stable element into a different element by hitting its nucleus with particles such as alpha particles, protons, or neutrons using devices like particle accelerators -non spontaneous - two or more reactants on left side
define nuclear fission a heavy atomic nucleus, such as uranium or plutonium, splits into two smaller nuclei, releasing a significant amount of energy in the process
nuclear fission benefits High‑energy output from small fuel amount. low greenhouse gas emissions. Long‑term, reliable energy supply Efficient energy conversion Applications in chemistry and industry
nuclear fission disadvantages -radioactive wastes -risk of accidents
define nuclear fusion the process where two light atomic nuclei combine to form a heavier nucleus, releasing energy due to the conversion of mass into energy.
nuclear fusion advantages in short, fusion offers a way to produce huge amounts of energy from simple, abundant fuels without the pollution and long-term waste problems of current energy sources.
nuclear fusion disadvantages unable to be attained
what is mass defect? Mass defect is the small amount of mass that “disappears” when protons, neutrons, and electrons come together to form an atom — and it’s the source of the energy that holds the nucleus together.
what is half-life? is the time it takes for the amount of a substance to reduce to half of its initial value. -completely unaffected by external environmental conditions such as changes in temp, pressure, or chemical bonding
Created by: user-1550741
 

 



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