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electrochemistry
| Question | Answer |
|---|---|
| electrochemistry | study of oxidation-reduction reactions that involve the transfer of electrons |
| electric charge | property of matter (C) (COULOMB) |
| protons and electrons | very small charge (+-1.602 x 10^-19 C) |
| electric field | force per unit charge N/C opposite charges attract, like charges attract |
| electric potential | ability of an electric field to do work on a charge (V=J/C) **important; need to know this and the unit** |
| electric current | rate charge flow (A=C/s) |
| oxidation | when electrons are lost when oxidation number increases LEO |
| reduction | when electrons are gained losing/reducing oxidation number |
| electrochemical cells and types | system of electrodes (often metals) and electrolytes in which a chemical rxn generates or uses an electric current voltaic (galvanic) cell electrolytic cell |
| voltaic (galvanic) cell | an electrochemical cell that uses a SPONTANEOUS reaction to generate electric current |
| electrolytic cell | an electrochemical cell in which an external energy source drives a non spontaneous rxn “takes a nonspontaneous rxn and uses an external power source to drive the rxn” |
| redox rxn | transfer of electrons |
| half cells | when you split up a redox rxn and have 1 half rxn in one beaker and other rxn in other beaker portions of the voltaic cell where the separated half rxns take place |
| oxidation occurs at the | anode |
| reduction occurs at the | cathode |
| reduction does what to electrons | consumes electrons (+) |
| oxidation does what to electrons | produces electrons (-) |
| salt bridge | allows ions to flow and balance charge |
| how do ions flow in the salt bridge | anions flow toward the anode cations flow toward the cathode |
| salt bridge purpose | to maintain charge balance not of electrons but rather ions i guess idk... electrons go via wire, not this i guess if we didnt do this, rxn would stop itself so theres no "charge buildup" |
| oxidation potential | ability of the anode to lose e- Eox |
| reduction potential | ability of the cathode to gain e- Ered |