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chem exam 4
| Question | Answer |
|---|---|
| coordinate covalent bond | the bond that occurs when 1 atom transfers an electron pair to another seen formed between Lewis acids/bases |
| dative bond | other term for coordinate covalent bond |
| lewis acid-base adduct | the compound that forms when you make a coordinate covalent bond/ when a lewis acid/base react compound that contains a coordinate bond between the lewis acid & base |
| complex ion | formed when a metal cation and lewis base react to transfer electrons and therefore form a coordinate covalent bond "ion formed from a metal ion with a lewis base via a coordinate covalent bond" to be proper... |
| ligand | the lewis base that bonds with a metal ion to form a complex ion |
| stability constant | aka formation constant Kf |
| dissociation constant | Kd |
| solubility product constant | Ksp at a compounds Ksp value, the solution is exactly saturated any lower of a value and a precipitate forms "the max amount of solute that can be dissolved in water before solid forms" |
| molar solubility | s molarity of a SATURATED solution |
| ion product | Qc solubility product expression evaluated |
| how to convert s between g/L to mol/L and vice versa; what molar mass do you use? | use the molar mass of the compound solid that is dissociating/ the precipitate |
| smaller Ksp | LESS soluble won't dissociate very much we like when Ksp is small cause we can neglect x 😛😛😛 |
| how do common ions affect solubility | when a common ion is added, solubility decreases because it pushes reaction left towards the solid reactant; more precipitate formed aka less soluble |
| lewis acid | ACCEPTS electron pairs |
| lewis base | DONATES electron pairs |
| larger Ksp | much more soluble |
| low ksp means | its mostly reactants at equilibrium aka,,,,not very soluble |
| when CAN you make the assumption to neglect x | if its just being added to another number and Ksp is hella small ex: 0.010 + x |
| when CANT you make the assumption to neglect x | if its involved in multiplication or division, or if its alone (and Ksp is hella small) ex: x, 2x, 4x, etc |
| what makes good Lewis acids | cations and electron deficient species |
| what make good Lewis bases | anions |