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Chem 107 Exam 2
| Term | Definition |
|---|---|
| synthesis reaction | A+B --> AB marriage |
| decomposition reaction | AB --> A + B divorce |
| single replacement | AX + B --> A + BX bad prom |
| double replacement | AX + BY --> AY + BX switching partners |
| always soluble | 1A (Li, Na, K, Rb, Cs) NH4+ NO3- acetate (C2H3O2-) ClO4- |
| everything is soluble with Cl-, Br-, I- except | Ag+, Pb2+, Cu+ and Hg2+ |
| everything is soluble with SO4 2- except | Ca2+, Sr2+, Ba2+, Pb2+ |
| OH- solubility | insoluble (except 1A, NH4, Ca/Sr/Ba 2+) |
| CO3 2- and PO4 3- solubility | insoluble (except group 1A and NH4) |
| S2- | insoluble (except group 1A and NH4 and Ca/Sr/Ba 2+) |
| O2 gas glowing splint burning splint | O2 gas glowing splint - reignite burning splint - stay burning |
| CO2 gas glowing splint burning splint | CO2 gas glowing splint - distinguished burning splint - distinguished |
| H2 gas glowing splint burning splint | H2 gas glowing splint - nothing really burning splint - pop/explosion |
| water and electricity | decomposition 2H2O --> 2H2 + O2 |
| copper (II) chloride and aluminum | 3CuCl2 + 2Al -->2AlCl3 + Cu single replacement |
| lead (II) nitrate and potassium iodide | Pb(NO3)2 + 2KI --> PbI + 2K(NO3) double replacement |
| sodium and chlorine gas | 2Na + Cl2 --> 2NaCl synthesis |
| magnesium and air | 2Mg + O2 --> 2MgO synthesis |
| magnesium oxide and water | MgO + H2O --> Mg(OH)2 synthesis |
| sodium hydrogen carbonate | NaHCO3 --> NaCO3 + H2O + CO2 decomposition |
| hydrogen peroxide | 2H2O2 --> O2 + 2H2O decomposition |
| silver nitrate and copper | Ag(NO3) + Cu--> Cu(NO3) + Ag single replacement |
| hydrochloric acid and zinc | 2HCl +Zn --> ZnCl2 + H2 single replacement |
| sodium carbonate and calcium nitrate | Na2CO3 + Ca(NO3)2 --> Ca(CO3) + 2Na(NO3) double replacement |
| sodium hydroxide and copper (II) sulfate | 2NaOH + Cu(SO4) --> Cu(OH)2 + Na2SO4 double replacement |
| what is equilibrium | constants of reactant and products are constant (not equal!) forward and reverse reactions are the same rate |
| Le Chatlier's equation | lnKeq = -deltaH/R (1/T) + deltaS/R |
| when you increase pressure you _______ volume, which means the equilibirum shifts to the side with ____ gas moles | when you increase pressure you decrease volume, which means the equilibirum shifts to the side with less gas moles |
| when m is positive | delta H is negative |
| electrons have spin which gives them a tiny ______ _______ unpaired electrons have no other electron to cancel out their spin making them ______ | electrons have spin which gives them a tiny magnetic field unpaired electrons have no other electron to cancel out their spin making them magnetic |
| paramagnetic | at least one unpaired electron, attracted by magnetic fields |
| diamagnetic | no unpaired electrons slightly repelled by magnetic fields |
| formation of ferrofluid | FeCl2 + 2FeCl3 + 4H2O --> Fe3O4 + 8HCl |
| 2 roles of ammonia | 1 NH3 is a base, neutralizes the acid HCl this makes the acid "go away" and equilibrium shifts to the right making more product 2 add ammonia slowly to avoid large clumps of precipitate and to actually form small bits of nanoparticles |
| surfactant | nanoparticles in water clump together because of magnetic attraction surfactant coats them to prevent clumping |
| surfactant - tetramethylammonium hydroxide | the hydroxide (-) sticks to the magnetite and the (+) TMA is on the outside repelling each other |
| Fe2+ | 3d6 II I I I I I |
| Fe3+ | 3d5 I I I I I I |
| magnetite and a magnet forms spikes because | the magnetic force pulls up and surface tension pulls down the fluid climbs up the magnetic field lines |
| how to measure in a graduated cylinder | to the nearest two decimal places, must be an even number |
| conductivity titration curve | very high with a strong acid completely dissociated goes down as acid is made up into base goes back up at equivalence point after more OH- has been made |
| temperature exothermic endothermic | exothermic - goes up (releases heat) and then cools down to room temp after eq point endothermic - goes down (uses up the heat) and then heats back up to room temp |
| equation showing colorless to red | Fe3+ + SCN- --> FeSCN 2+ + heat |
| colorless solution means | no absorbance (because all wavelengths were transmitted and none were absorbed) |