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Chapter 14

General Chemistry 2 Spring Semester 2026

QuestionAnswer
Define acid according to the Arrhenius definition A substance that produces H+ ions in aqueous solution
Define base according to the Arrhenius definition A substance that produces OH−ions in aqueous solution
Define neutralization Acids and bases combine to form water
Define acid according to Brønsted–Lowry Acid–Base Theory Proton (H+ ion) donor
Define base according to Brønsted–Lowry Acid–Base Theory Proton (H+ ion) acceptor
Define conjugate acid-base pair Two substances related to each other by the transfer of a proton
What does a conjugate acid-base pair differ by? 1 proton
A base accepts what to become a conjugate ___ A base accepts a proton and becomes a conjugate acid
A acid accepts what to become a conjugate ___ An acid donates a proton and becomes a conjugate base
What always appear appear together in a na acid-base reaction? Acids and bases
Define amphoteric. Give an example. Substances that can act as acids or bases H2O
Define monoprotic acids. Give an example. Contain only one ionizable proton
Define diprotic acids. Give an example. Have two ionizable protons
Define triprotic acids. Give an example. Have three ionizable protons
What may polyprotic acids yield? In what manner? What is written for each stage? Polyprotic acids may yield more than one hydrogen ion per molecule.Ionize in a stepwise manner; that is, they lose one proton at a time An ionization constant expression can be written for each ionization stage
Define autoionization Pure water acts as an acid and a base with itself
Define ion product constant for water, Kw The equilibrium constant for the autoionization of water
What happens to strong acids when placed in an aqueous solution? Strong acids fully ionize (fully dissociate) in aqueous solutions
What happens to weak acids when placed in an aqueous solution? Weak acids partially ionize (dissociate) in aqueous solutions
What are the six strong acids? HCl (hydrochloric acid) HBr (hydrobromic acid) HI (hydroiodic acid) HNO3 (nitric acid) HClO4 (perchloric acid) H2SO4 (sulfuric acid)
What are the six weak bases? HF (hydrofluoric acid) CH3COOH (acetic acid) HCOOH (formic acid) H2SO3 (sulfurous acid) H2CO3 (carbonic acid) H3PO4 (phosphoric acid)
Define acid ionization constant. What variable is used? The equilibrium constant for the ionization reaction of the weak acid
What happens as Ka gets larger? Larger Ka means a stronger weak acid
What happens to pKa as Ka get larger? What about the weak acid? The larger the Ka, the smaller the pKa, the stronger the weak acid
What happens to pKa as Ka get smaller? What about the weak acid? The smaller the Ka, the larger the pKa, the weaker the weak acid
What do weak bases produce? How? What do they form? Produce OH− by accepting protons from water, ionizing water to form OH−
What do most weak bases have? What does it do? Most of the weak bases have a nitrogen atom with a lone pair, which accepts protons (H+) from water to make the substance a base
Define base ionization constant? What variable is used? The equilibrium constant for the ionization of a weak base Kb
What happens to the pKb as Kb get larger? What about the weak base? The larger the Kb, the smaller the pKb, the stronger the weak base
What happens to the pKb as Kb get smaller? What about the weak base? The smaller the Kb, the larger the pKb, the weaker the weak base
When there is a mixture of a strong acid and a weak acid what does the [H3O+] total equal? [H3O+] of the strong acid
When there is a mixture of a two weak acids what does the [H3O+] total equal? [H3O+] of the higher Ka acid
Define percent ionization (for a weak acid) The ratio of the ionized acid concentration to the initial acid concentration, multiplied by 100%
What results in a higher percent ionization for two acids of the same initial concentration The stronger weak acids results in higher percent ionizaiton
Define binary acids Contain hydrogen and only one other element (nonmetal) H−Y• Acid strength of binary acids
In what direction does binary acids increase when looking at the periodic table Increases from left to right and top to bottom
Define oxyacids Contain a hydrogen atom bonded to an oxygen atom that is bonded to another element
How does the oxyacid change as the number of oxygen atoms that are bonded to the same Y increase? The stronger the oxyacid
If there are the same number of oxygen atoms, what affects the oxyacid? For same number of oxygen atoms, the more electronegative (to the right, to the top) the element Y, the stronger the oxyacid
When the acid is strong what is its conjugate base? What is Ka? What is Kb? The acid is strong, the conjugate base is pH neutral Ka is very large Kb is about 0
When the acid is weak what is its conjugate base? The acid is weak, the conjugate base is weak
When the acid is very weak what is its conjugate base? What is Ka? What is Kb? The acid is very weak, the conjugate base is strong Ka is about 0 Kb is very large
Define salt A chemical compound consisting of an assembly of cations and anions
An anion that is the conjugate base of a weak acid is what kind of base? A weak base
An anion that is the conjugate base of a strong acid is ___ so it is ____ An anion that is the conjugate base (A−) of a strong acid is so weak it is pH-neutral
Cations that are counterions of strong bases are ___ pH neutral
Does a cation ionize in water? No
What is the relationship between A- and H+ in water? The conjugate base (A-) has a high affinity to H+ in water
Cations that are the conjugate acids of weak bases are what kind of acids? Weak acids
Cations that are small, highly charged metals form what kind of solution? Acidic solutions
Created by: KristenR2025
 

 



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