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Chapter 13
General Chemistry 2 Spring Semester 2026
| Question | Answer |
|---|---|
| Define a reversible reaction | Processes that proceed in both the forward and reverse direction |
| Define dynamic equilibrium | The condition in which the rate of the forward reaction equals the rate of the reverse reaction |
| What do longer changes in a dynamic equilibrium | The concentrations of reactants and products no longer change |
| Why is the equilibrium dynamic? What is changing? | • Reactants become products • Products become reactants • Both happen at the same rate |
| Qualities of an equilibrium | All chemical reactions will eventually reach equilibrium Equilibrium can be: Almost all reactants, Almost all products, Or somewhere in between Equilibrium describes how much of the products are formed |
| Define Equilibrium Constant | The ratio of the equilibrium concentrations of the products raised to their stoichiometric coefficients divided by the equilibrium concentrations of the reactants raised to their stoichiometric coefficients |
| How is the equilibrium constant expressed | Equilibrium tends to be expressed as a ratio of products to reactants |
| What is K related to equilbirum | K is the equilibrium constant for this reaction K is a constant for a given chemical reaction (at a given temperature)K is different for every chemical reaction |
| What is a heterogeneous equilbiria? | Reaction that includes different phases |
| What is not included in the equilibrium constant expression? | Solids and liquids |
| If Q > K then | Too much products Reactants will form until equilibrium reached Reaction moves to the left |
| If Q < K then | Too much reactants Products will form until equilibrium reached Reaction moves to the right |
| If Q = K then | then equilibrium is reached |
| If K is very large | Almost all products Very little reactants |
| If K is around 1 | Almost equal amounts or products to reactants |
| If K is very small | Almost all reactants Very little products |
| If the equation is manipulated what else is? | K |
| If the equation is doubled what is done to K? | It is squared |
| If the equation is halved what is done to K? | It is raised to the 1/2 |
| If the equation is flipped what is done to K? | It is raised to the negative 1 |
| How can we expresses the equilibrium in a gaseous reaction? | The ratio of the concentrations, or the partial pressures of the gases. |
| Δn equation | Δn = (products) - (reactants) Only for gases |
| What can Le Châtelier's principle be used for? | To predict changes in equilibrium concentrations when a system that is at equilibrium is subjected to a stress. (i.e. a disturbance occurs) |
| What does Le Châtelier's principle say? | When equilibrium is disturbed the reaction will proceed to minimize the disturbance |
| What are some of the disturbances of Le Châtelier's principle? | Adding reactant Adding product Removing reactant Removing product |
| What happens when reactant is removed to a solution according to Le Châtelier's principle? | Moves to the right, turn reactant into product |
| What happens when reactant is added to a solution according to Le Châtelier's principle? | Reaction moves to the left, turning products back to reactants |
| What happens when product is added to a solution according to Le Châtelier's principle? | Reaction moves to the left, turning products to reactants to recover the lost reactant |
| What happens when product is removed to a solution according to Le Châtelier's principle? | Reaction moves to the right, to recover lost product |
| If the reaction is exothermic what will happen if you raise the temperature? | Shifts to the left (less product formation) and more reactant production |
| If the reaction is exothermic what will happen if you lower the temperature? | Shift to the right (more product formation) and less reactant production |
| If the reaction is endothermic what will happen if you raise the temperature? | Shifts to the right (more product formation) and less reactant production |
| If the reaction is endothermic what will happen if you lower the temperature? | Shifts to the left (less product formation) and more reactant formation |
| What happens to K with a shift to the right? | K got larger |
| What happens to K with a shift to the left? | K got smaller |
| What does pressure effect in an equilibrium? | Only affects gas |
| How is pressure manipulated in an equilibrium? | By changing the volume |
| How do you raise the overall pressure? What does the reaction do? | Decrease volume Reaction will try to minimize the number of gas moleulces |
| How do you lower the overall pressure? What does the reaction do? | Lower volume Reaction will try to maximize the number of gas molecules |
| What happens when you add an inert gas to an equilibrium? What does it effect? | Adding an inert gas to raise the pressure of a reaction container does not shift the equilibrium. It does not effect the concentration of gases |
| How do catalysts affect the equilibrium? | Catalysts don’t effect equilibrium |