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Reagants
Pset 7 and 8
| Question | Answer |
|---|---|
| Jones | turns primary and secondary methyl groups into carboxylic acids (cooh) |
| kmno4, h+, h2o | turns primary and secondary methyl groups into carboxylic acids (cooh) |
| nbs, ch2cl2, hv | bromination at benzylic position |
| bromination of an aromatic | br2, febr3 |
| chlorination of an aromatic | cl2, alcl3 |
| sulfonylation of an aromatic | so3, h2so4 OR fuming h2so4 |
| nitration of an aromatic | hno3, h2so4 |
| what reactions can turn no2 into nh2 | sncl2, hcl, naoh fe, hcl, naoh h2, pd/c zn/hg, hcl |
| reagants for benzynes | need to have LG on molecule nanh2, nh3 mg(o), thf csf, sime3 |
| suzuki reaction | (ph3p)4pd k2co3, h2o, phme |
| stille reaction | (ph3p)4pd ch2cl2 |
| kumada reaction | (ph3p)4pd, thf mgbr |
| what does h2o, h+ do for an aldehyde | adds 2 OH grps |
| what does meoh and h+ do to an aldehyde | adds two ch3o groups |
| how to get rid of protecting groups/ ring protecting groups (acetal) | h2o, h+ |
| what does raney nickel do | replaces a group w hydrogen (ex: sme, ome, etc...) |
| what does hgcl2 do with h2o to thiol (sme) groups | makes into ketone |
| what does mcpba, ch2cl2 do | ketones to esters aldehydes to carboxylic acids |
| how to reduce a ketone into two H | n2h4, temp, NAOH, diglyme |
| how to turn an aldehyde into a carboxylic acid | naclo2, nahpo4 |
| how to turn a carboxylic acid into a rocl | socl2 |
| how to turn |
Created by:
kavyasurav