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chem exam 3
chemical equillibrium
| Question | Answer |
|---|---|
| chemical equilibrium | a state reached by a reaction mixture when the forward and reverse reaction rates become equal its a type of state, a condition of the symptom no net change between reactants and products; their CONCENTRATIONS are steady and equal |
| with what kinds of reactions can chemical equillibrium occur | reversible reactions |
| reversible reactions | yield a mixture of reactants and products |
| dynamic equilibrium | forward and reverse reactions occur with equal rate, such that there is no net change in composition (at macro level anyway) everything well be working with is dynamic equillibrium |
| is anything happening when a reaction is at equillibrium? | at a microscopic level, forward and backward reactions are occurring, things continue to change but at macroscopic level theres no net change |
| what does equilibrium composition depends on | initial concentrations temperature (particularly important) pressure volume (pressure and volume are mainly for gases) |
| equilibrium constant | Kc |
| does the equilibrium constant depend on initial concentrations | no |
| equilibrium constant units | ITS UNITLESSSSS GET PRANKKKEDDDDD |
| what does equilibrium constant depend on | not initial concentrations but rather temperature |
| how do you know if a rxn is at equilibrium | the reaction rates are equal/the same for each side (rxn keeps going on but at equal rates so theres no net change) no net change in concentrations (dont necessarily have to be equal) |
| if the cocnentrations of products and reactants are equal, is the system at equilibrium? | not necessarily to characterize a rxn as at equilibrium, concentrations need to be CONSTANTLY but do not need to be equal |
| reversible rxns need to be in what kind of container for equilibrium to be met | closed closed system otherwise something will escape and concentrations can be constant if you’re losing some |
| when is partial pressure used | to express equilibrium constant for gaseous reactions |