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ochem exam 1

QuestionAnswer
organic chemistry study of carbon + carbon related compounds
ionic bond between a metal and nonmetal
covalent bond between two nonmetals
polar EN difference of 0.5 to 1.5
nonpolar EN difference of 0-0.4
Electronegativity (EN) an atom's ability to attract electrons
Carbon EN 2.5
Nitrogen EN 3.0
Oxygen EN 3.5
Hydrogen EN 2.1
how many times does carbon bond? 4!!!!
halogens Fluorine, Bromine, Chlorine, Iodine
alkanes C-C and C-H
Alkenes C=C
Alkynes C≡C
Aromatic/ benzene 6 member carbon ring with alternating double bonds
heterocyclic aromatics satisfy all rules of aromaticy, but contain other atoms (such as N and O) within the ring
Alcohols O-H
Ketones C / O=C \ C
aldehydes H / C=O \ C
Ether C-O-C
Ester C=O attached to a C-O-C
carboxylic acid O=C + O-H
amine N-H
amide N-H and C=O
alkyl halides alkane + halogen
saturated has the max numbers of hydrogens
unsaturated has less than the max number of hydrogens (has double or triple bonds between carbons)
constitutional isomers same formula different appearance
IUPAC international union of pure and applied chemistry
1 meth
2 eth
3 prop
4 but
london dispersion forces (LDF) momentary dipoles caused by the random movement of electrons; weakest of all three; all molecules have these
dipole-dipole fixed dipoles (think magnet); stronger than LDF but fewer
hydrogen bonding hydrogen attached to a nitrogen or an oxygen attached to another nitrogen or oxygen
Alkane intermolecular forces LDF only not polar so no dipole-dipole no O's or N's so no hydrogen bonds
what raises LDF adding carbons, which raises boiling point
branching causes ___________ intermolecular forces lower; gives lower melting and boiling points too
alkanes physical properties odorless, tasteless, colorless; less dense than water; not soluble in water (nonpolar); nontoxic
alkanes reactivity burn for energy (exothermic)
products of alkanes in a chemical reaction H2O + CO2 + heat
pi bond additional bonds after the first initial sigma bond
cis-trans isomerism when the carbons in an alkene (C=C) have 2 different substituent groups; the double bond does not rotate
cis the hydrogens are on the same side
trans similar groups on opposite sides
E/Z naming isomers of double bonds that aren't cis or trans; the one with the higher difference makes the highest priority
addition reactions 2 reactants combine to form 1 new product
Hydrogenation add hydrogen
catalysts for hydrogenation nickel (Ni), Palladium (Pd), Platinum (Pt)
Halogenation Add either Br2 or Cl2
Halogenation of bromine bromination
halogenation of chlorine chlorination
atomic number number of protons
Hydrohalogenation addition of H-Br or H-Cl
hydration addition of H2O
markovinikov's regioselectivity when adding a hydrogen it adds to the carbon that already has the most H's
common names for alkynes acetylene is always last
hydrogenation turns an alkene to an alkane
what should you use to convert propene to 2-chloropropene
Created by: kingsleya27
 

 



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