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alkene rxns
| Question | Answer |
|---|---|
| what are the two groups added for hydrohalogenation | h+x |
| what are the reagants for hydrohalogenation | hX (with x being cl, br, i) and a non reactive, inert solvent thats not h2o or ROH |
| is there any stereochem for hydrohalogenation | no, d/t chiral centers |
| what is the regiochem for hydrohalogenation | markovnikov |
| does hydrohalogenation have carbocation rearrangement | yes |
| is hydrohalogenation reversible | yes |
| what are the two groups added for hydrohalogenation with a radical | h+br |
| what are the reagants for hydrohalogenation with a radical | hbr/RooR |
| is there any stereochem for hydrohalogenation with a radical | no, d/t chiral centers |
| what is the regiochem for hydrohalogenation with a radical | anti markovnikov |
| does hydrohalogenation with radical have carbocation rearrangement | no |
| what are the two groups added for acid catalyzed hydration | h+oh |
| what is the reagants for acid catalyzed hydration | h2so4 |
| is there any stereochem for acid catalyzed hydration | no |
| what is the regiochem for acid catalyzed hydration | markovnikov |
| is there carbocation rearrangements in acid catalyzed reactions | yes |
| what is the groups added for oxymercuration demercuration | h+oh |
| what are the reagants for oxymercuration demercuration | 1. hg(oac)2, h2o/roh 2. h2o2, naoh |
| is there any stereochem for oxymercuration demercuration | anti |
| what is the regiochem for oxymercurration demercuration | markovnikov |
| is there carbocation rearrangements for oxymercuration demercuration | no |
| what are the groups added for hydroboration oxidation | h+oh |
| what are the reagants for hydroboration oxidation | 1. bh3, thf 2. h2o2, naoh |
| is there any stereochem for hydroboration oxidation | syn |
| what is the regiochem for hydroboration oxidation | antimarkovnikov |
| is there carbocation rearrangement for hydroboration oxidation | no |
| what are the two groups added for halogenation | x+x |
| what are the reagants for halogenation | x2, chlorinated solvent ( no h2o or roh) |
| is there any stereochem for halogenation | anti |
| what is the regiochem for halogenation | none |
| is there carbocation rearrangement for halogenation | no |
| what groups are added for catalytic hydrogenation | h+h |
| what are the reagants for catalytic hydrogenation | h2/pt |
| is there any stereochem for catalytic hydrogenation | syn |
| what is the regiochem for catalytic hydrogenation | none |
| is there any carbocation rearrangement for catalytic hydrogenation | no |
| what are the two groups for halohydrin formation | x+oh |
| what are the reagants for halohydrin formation | x2/h2o or roh |
| is there any stereochem for halohydrin formation | anti |
| what is the regiochem for halohydrin formation | none |
| is there carbocation formation for halohydrin formation | no |
| what are the two groups for anti didyhydroxylation | oh+oh |
| what are the reagants for anti dihydroxylation | 1. rco3h 2. h3o+ |
| is there streochem for anti dihydroxylation | anti |
| what is the regiochem for anti dihydroxylation | none |
| what is the groups added for syn dihydroxylation | oh+oh |
| what are the reagants for syn dihydroxylation | oso4, nmo |
| is there stereochem for syn dehydroxylation | syn |
| what is the regiochem for syn dehydroxylation | none |
| what are the two groups for oxidation cleavage | none |
| what are the reagants for oxidative cleavage | 1. o3, 2. dms |
| is there any stereochem for oxidative cleavage | no |
| what is the regiochem for oxidative cleavage | no |
Created by:
kavyasurav