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CH 223 Exam 1

CH 12-14

TermDefinition
zero order diff equation [A]t = [A]0 -kt
first order diff equation [A]t = [A]0 e^-kt
second order diff equation 1/[A]t = 1/[A]0 +kt
zero order integrated rate law [A]0 / 2k
first order integrated rate law ln(2) / k
second order integrated rate law 1/k[A]0
Arrhenius equation k = A * e^-RT
gibbs free energy deltaG = deltaH - deltaTS
rate order rate = k[A]^x[B]^y
H (+) S (-) G (+) = nonspontaneous
H (-) S (+) G (-) = spontaneous
H (-) S (-) G (- or +) low temp - spontaneous high temp - nonspontaneous
H (+) S (+) G (- or +) low temp - nonspontaneous high temp - spontaneous
Created by: linju156
 

 



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