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MMET Lecture 3

QuestionAnswer
What are the 2 principles of iron ores? Hematite (Fe_2O_3) & magnetite (Fe_3O_4)
What is taconite? Siliceous rock containing fairly low-volume concentrations of iron.
What is pelletizing? When rocks are sintered into small balls about 1/2 in in diameter. Iron %: 70% or greater.
What is a blast furnace & what does it do? A multistory heated reaction vessel to reduce iron ore to steel (1st step). Iron freed from most impurities. Charged with iron ore, limestone, & coke. Slag protects from oxygen.
What are the equations of the production of the reducing gas? C (coke) + O_2 (air) -> CO_2 (carbon dioxide) CO_2 +C (excess coke )-> 2CO (carbon monoxide)
What are the equations of the reduction of the iron oxide? 2 Fe_2O_3 (ore) +3C (coke) -> 4Fe + 3CO_2 Fe_2O_3 + 3CO (carbon monoxide) ->2Fe (iron) + 3CO_2 (carbon dioxide)
What is pig iron? Impure, high carbon content, & not suitable for making engineering materials because it would be extremely brittle & weak. Has 3-5% carbon, rest is iron & some impurities.
What are direct reduction processes?
What is the iron carbide process?
What is a basic oxygen furnace (BOF) furnace? A steelmaking process that reduces impurities in steel. Charged with scrap, pig iron, & hot metal. Cheaper. Continuous.
What is steel? An alloy of iron & carbon 0.06%-2.0%. combination of iron & carbon.
What is pure iron? Soft, ductile, & weak. Used for magnetic devices & enameling steels.
What is the lowest carbon content for steels? 0.06%
What are cast irons? Have more than 2% C.
What happens if alloys have high carbon content? It makes them too brittle for any fabrication techniques besides casting.
What is oxidation? Removes impurities from pig iron.
What is an electric arc furnace (EAF)? Uses heat & charged with scrap or pig iron. Better, but expensive
What is continuous casting? Skips the ingot step. Used for tool steels. Produces rounds, squares, slabs, & plates. Improved yield, quality, productivity, & cost efficiency. 2 hrs
What are inclusions? Oxides, silicates, sulfides, or aluminas that form during conventional melting & refining.
What is vacuum degassing? Removes dissolved gases from steels.
What is deoxidation? removal of oxygen from molten steel
What is ladle heating? Restores heat to the metal in the ladle.
What is vacuum arc remelting (VAR)? Involves casting of steels from the BOF or electric furnace into cylindrical ingots. Removes inclusions.
What is vacuum induction melting (VIM)? Melts solid scrap/liquid charges.
What is electron beam refining? Vaporizes impurities so that they can be removed as vapors in the vacuum.
What is the AOD process?
What is electroslag refining? Similar to VAR, but w/out the vacuum.
What is purification? Accomplished when melting metal from the ingot passes through a molten flux that acts like a welding electrode slag to remove impurities.
What is segregation? A variation in chemical composition.
What is pipe? A cavity in the top of an ingot.
How is pipe formed? By volumetric shrinkage of the metal as it transforms from liquid to solid.
What is rimmed steel? Ingots that solidify w/ a skin that is purer than the center. Slightly deoxidized steels that solidify w/ outer shell on the ingot which is low in impurities. Can retain a good finish after severe forming because of the surface cleanliness. Very ductile & malleable - can be shaped.
What are killed steels? Less prone to problems. Strongly deoxidized by chemical additions to the melt. Very few inclusions & little porosity.
What metal is always killed/deoxidized? Continuous cast steels
What are concerns with continuous cast steels? Inclusions, porosity, segregation, & grain size
What are strands? Solidify w/ a grain structure
What is a dendrite? 3-D treelike structure. Nature's way of solidifying. A significant part of the basic metallurgy. Can form from nuclei that can be a single atom, impurity, or protrusion from the mold wall, etc.
What is a grain boundary? When grains/crystallites meet.
Grain size relates to? Strength
Small grain size = Higher strength
Large grains = Weaker strength
What are equiaxed grains? Grains that have the same shape in the x, y, & z directions.
How are steels shaped? By hot rolling, or hot/cold-finished from a steel mill
What shapes can hot rolling produce? Billets, blooms, & slabs
What is the metallic bond? Atoms that are held together by an electron cloud
What is plastic deformation? By atomic movement (slip) in each crystal/grain that is in the metal shape
What is solidification? Dendrites -> crystals
What is a phase? Homogeneous component of a solid/liquid/gas that is separated from other phases by an interface. Happens after solidification. More dendrites & grains will be formed.
Billets can become? Bars, rods, or tube rounds
Bars are used for? Cold-drawn bars
Rods are used for? Wire
Tube rounds are used for? Seamless pipes
Blooms can become? Tube rounds, structural shapes, or rails
Rails are used for? Cold-rolled sheet & strip
Slabs can become? Skelps or plates; Hot-rolled sheet & strip for tin mill products
Skelp is used for? Welded pipe & tubing
Plates are used for? Large-diameter pipe
What is recrystallization? Grains grow back when the steel is red hot after being squashed. Occurs in annealing.
The more the grains are squashed..? The harder the steel gets
Fracture will occur if..? Additional reduction/shaping is attempted
What is hot finishing? Ingots/continuous cast shapes are rolled in the red-hot condition to smaller shapes such as blooms or billets. Makes steels soft, but mechanical properties are very low.
What is cold finishing? Much stronger mechanical properties & better surface finish than hot finished steels.
Hot finished, low carbon steel may have a tensile strength of? 60 ksi
A full, hard, cold finished steel may have a tensile strength of? 120 ksi
What is a carbon steel? Steel with a carbon as the principal hardening agent. All other alloying elements are present in small %s. Max %: Maganese - 1.65%, Silicon - 0.60%, Copper - 0.60%, Sulfur & Phosphorus - 0.05%
What is an alloy steel? Steels w/ total alloy additions of less than ~5%. Used for structural applications/
How are killed steels produced? Elements are added to the steel, such as aluminum & silicon, that remove dissolved oxygen from the molten metal & alter the ingot solidification characteristics to minimized segregation.
What are galvanized steels? Zinc-coated steel. Zinc is applied by hot dipping.
What are galvannealed steels? Zinc-coated & heat-treated steels. Has an oxide layer that allows better paint adhesion.
What is a free machined steel? Steels w/ additions of sulfur, lead, selenium, or other elements in sufficient quantity that they machine more easily.
What is Commercial Quality? Steels produced from standard rimmed, capped, concast, or semiskilled steel.
What are H steels? Made to guarantee ability to harden to a certain depth in heat treatment,
What are B steels? Steels w/ small boron additions as a hardening agent.
What is pickling? Use of acids to remove oxides & scale on hot-worked steels
What is temper rolling? Involves a small amount of roll reduction to eliminate stretcher strains
What is temper? The amount of cold reduction in rolled sheet & strip
What are E steels? Melted by electric furnace
What is the product of the blast furnace? Pig iron
What is the 1st step of steelmaking? Iron ore must be reduced from its oxide form in a blast furnace
Iron ore is the source of the..? Iron oxide
What is C + O_2 -> CO_2? Combustion creating heat
What is the source of the pure carbon? Coal/Coke
What is CO_2 + C -> 2CO Produces the carbon monoxide that when combined w/ the iron oxide in Fe_2O_3 + 3CO -> 2Fe + 3CO_2 preferentially bonds with the oxygen thus yielding more iron & carbon dioxide
Limestone is added to the blast furnace for what purpose? It forms slag that helps draw out impurities that can be removed.
A blast furnace & a basics oxygen furnace do the same thing? False
Chemical segregation during ingot solidification usually leads to a variation of mechanical properties across the cooled ingot. True
An allotropic material can have 2 or more crystalline forms in the same phase. True
The charpy impact test is used to determine the sensitivity of a metal's impact strength to changes in _? Temperature
A basic oxygen furnace must have a change of molten metal, can use recycled steel & used an oxygen lance to make steel? True
As carbon content increases in steel, the strength & ductility increase. False
What is low carbon alloy steel? 0-30 pts of carbon
What is alloytropism? The conversion to FCC or BCC
What is the key to MMET-207? Carbon
What is a body centered cubic (BCC)? Pearlite, holds less carbon
What is a face centered cubic (FCC)? More brittle, above AC_3, holds more carbon, stronger & harder
How do you get BCC -> FCC -> BCT? Quench
What is a BCT? Martensite
An electric arc furnace & a basic oxygen furnace make? Steel
What are raw materials? Iron ore mined & crushed into tiny pieces
What is limestone? Serves as flux, cleans out impurities & floats to the surface.
What is coke? Coal, pure form of carbon, supplies heat for smelting iron in blast furnaces, hard, brittle substance consisting of carbon
What is steel refining? Uses basic oxygen furnace (BOF) or electric arc furnace (EAF). May use pig iron, liquid pig iron, or scrap steel
Oxygen process After scrap & hot metal are charged into furnace, dust cap is put on, & oxygen blown through the lance to the surface of the molten metal in order to burn out impurities.
Steel scrap BOF uses this. Integrated producer.
Electric arc furnace (EAF) processes Can produce more than 800 tons of steel in 24 hrs, electricity used for production of heat, uses 3 carbon electrodes for direct arc, circular furnace shape which can be tilted to pour molten steel into ladle
Cast steel Made by molten steel casts in molds
What is the sequence of the type of steels from least refinement to most refinement? Rimmed - Capped - Semikilled - Killed
What are capped steels? Thin low carbon rim, remainder of cross section approaches degree of semikilled steels
What are semikilled steels? Intermediate in deoxidization between killed & rimmed, composition more uniform than rimmed steels
What are killed steels used for? Forging, piercing, carburizing, heat treatment, or continuous cast
What are the steps of casting? 1. Tundish to feed liquid steel to mold. 2. Primary/secondary cooling zone to generate solidified outer shell/the strand 3. Unbending & straightening 4. Severing unit to cut solidified strand
What are the different processes? Vacuum degassing, ladle stirring injection, & ladle furnace reheating
What do vacuum furnaces & degassing produce? High quality steel aloys
What are the advantages of vacuum furnaces & degassing? Less expensive, decreased amounts of hydrogen, oxygen, & nitrogen in finished product, improved mechanical properties, close heat control, & better hot & cold workability
Example of hot workability? Recrystallization
Example of cold workability? Dent your truck
What is ladle degassing? Ladle of molten steel placed in tank & then air removed from tank, exposing it to vacuum
What are special refining processes? Vacuum arc remelting (VAR), vacuum induction melting (VIM), electron beam refining, & electroslag melting (ESR)
What is Vacuum arc remelting used for? Super-alloys & extra clean steels
What is vacuum induction melting used for? Specialty alloys
What is electron beam refining used for? Purify specialty alloys
What is electroslag melting used for? Tool steels & special-purpose steels. Molten slag acts as a cleansing flux
What is a consumable electrode vacuum arc melting? Refining process for steels prepared by other methods. Steel electrodes or predetermined composition are remelted by an electric arc in air-tight, water-cooled crucible
What is vacuum induction melting? Charge melted in furnace within airtight, water cooled steel chamber
What are the advantages of vacuum induction melting? Freedom from air contamination, close control of heat, & few air inclusions
What is cold work? Residual stress, heated below AC_3
What is hot work? element alignment, heated above AC_3
What is forging? Reduces metal to desired shape, usually done with steam hammer, recrystallizing grains
What is drop forging? Piece of roughly shaped metal placed between die-shaped faces of exact form of finished piece - metal forced to take form by drawing dies together
Metalworking processes are..? All about the grain
What are metalworking processes? Shape & improve its characteristics: Forging & rolling. Destroy the cast structure.
What do metalworking processes do to steels? Make steels stronger, more ductile, & better shock resistance.
What is steel rolling? Steel wants to go back to equilibrium when energy (heat) is added creating rust/iron-carbide. Grains are oriented in direction of rolling.
What is hot rolling? Finished at temps between 900-2400 degrees F, black iron
What is cold rolling? Finished at room temperature, coated w/ Zinc (galvanized), tin (tin plate), tin & lead
What is piercing? Bar to pipe
What does rolling in the x direction do? Best strength & ductility
What does rolling in the y direction do? 30% reduction in strength & ductility
What does rolling in the z direction do? Lower strength, no ductility
What is drawing? Operation of reducing cross section & increasing length of metal bar/wire
What is extrusion? Forming by pressing through an opening, obtain perfectly round rods, metal places in closed chamber fitted w/ opening at 1 end & piston at the other end
Created by: Texi Rae
 

 



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