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chem
organics
| Question | Answer |
|---|---|
| -C=O | O-Na+ | carboxylate salt (-anoate) |
| -C=O | O | ester (-anoate) |
| -C=O | OH | carboxylic acid (-noic acid) |
| -C=O | Cl | acid chloride (-anoyl chloride) |
| -C=O | NH2 | amide (-anamide) |
| -C=O | ketone (-anone) |
| -C=O | H | aldehyde (-anal) |
| alkene + Br2 or Cl2 | haloalkane, addition |
| alkene + KMnO4 | diol, addition |
| alkene + H2/Ni cataylst | alkane, additon |
| alkene + H2SO4 (aq) or H+/H20 | alcohol, addition |
| secondary alcohol + H+/Cr2O72+ or H+/MnO4- | ketone, oxidation |
| primary alochol + H+/Cr2O72+ or H+/MnO4- | carboxylic acid, oxidation |
| aldehyde + benedicts/tollens/fehlings solution or H+/Cr2O72+ or H+/MnO4- | carboxylic acid, oxidation |
| alcohol + H2SO4 conc | alkene, elimination |
| haloalkane + KOH (alc) or NaOH (alc) | alkene, elimination |
| alcohol + SOCl2 or PCl5 or PCl3 | haloalkane, substitution |
| haloalkane + NaOH (aq) or KOH (aq) | alcohol, substitution |
| alkane + Br2 (aq) and UV light | haloalkane, substitution |
| haloalkane + NH3 conc. | amine, substitution |
| carboxylic acid + Na2CO3/NaHCO3 | carboxylate salt, acid-base |
| anime + dilute HCl or H2SO4 | ammonium salt, acid-base |
| alcohol + carboxylic acid with H2SO4 conc. cataylst | ester ("# of carbons in alcohol"-yl "# of carbons in carboxylic acid"- noate, esterification |
| aldehyde + NaBH4 | primary alcohol, reduction |
| ketone + NaBH4 | secondary alcohol, reduction |
| ester + HCl, H2SO4 (or H+) | alcohol + carboxylic acid, hydrolysis |
| ester + NaOH (aq) (or OH-) | alcohol + CO-, hydrolysis |
| amide + NaOH (aq) (or OH-) | COONa + NH3, hydrolysis |
| H+/Cr2O72- (with heat) observation | orange to green |
| acid chloride + NH3 conc | amide, substitution |
| acid chloride + H2O | carboxylic acid, substitution |
| carboxylic acid + PCl5, SOCl2, PCl3 | acid chloride, substitution |
| carboxylic acid + NH3 (aq) | ammonium salt, acid-base |
| acid chloride + alcohol + no reagent | ester, esterification |
| H+/MnO4- (with heat) observation | purple to colourless |
| MnO4- observation | purple to brown |
| Br2 water observation | orange to colourless |
| benedict's and fehlings solution (with heat) observation | blue to orange/brick red |
| tollens reagent (with heat) observation | colourless to a silver mirror forming |
| UI with amine observation | green to blue |
| UI with carboxylic acid observation | green to red/orange |
| NaCO3 and NaHCO3 with acid observation | bubbles of gas form |
| litmus paper and amine observation | blue |
| litmus paper and carboxylic acid observation | pink |
| amide pH | neutral |
| 6> carbon alcohol/carboxylic acid solubility | insoluble |
| function groups that form two layers with water (insoluble) | esters, hydrocarbons, and haloalkanes |
| water and acid chloride observation | violent reaction with bubbles and steamy fumes, HCl gas is released which turns blue litmus red (indicating it's an acid) |
| benedict's/tollens + alcohol | doesn't oxidise, they only oxidise aldehydes |
| polymer definition | large molecule made up of repeating units called monomers |
| addition polymerisation | the C=C in an alkene (unsaturated monomer) breaks and forms single bonds with adjacent monomers without losing atoms, producing only the polymer |
| condensation polymerisation | two small molecules/monomers react to form a polymer, and one water molecule is lost/eliminated for each ester or amide linkage formed |
| amino acid definition | monomers that have an amine group (-NH2), carboxylic acid group (-COOH), H, and variable R side chain all attached to the same carbon atom |
| peptide | 2 or more amino acids joined together |
| dipeptide | two amino acids joined together |
| polypeptide | 3 or more amino acids joined together |
| protein | natural polymer made up of long chains of amino acids joined together by peptide bonds |
| forming proteins | when the -NH2 group of one amino acid reacts with the -COOH group of another, undergoing a condensation reaction to form a peptide bond, and eliminating one molecule of H2O |
| breaking proteins | one H2O molecule is added per one peptide bond to break apart the amino acids, hydrolysis reaction |
| structural isomers | same molecular formula, different structural formula |
| geometric isomers | same molecular formula, different arragement in space |
| geometric isomer needs | C=C, 2 different bonded groups on each C atom in the double bond |
| cis-isomers (geometric) | groups of interest are on the same side of the C=C |
| trans-isomers (geometric) | groups of interest are on opposite sides of the C=C |
| optical isomers | same atoms and connectivity, but different 3D arrangement. they are non-superimposable mirror images of each other |
| optical isomer needs | chiral carbon (C with four different groups bonded to it) |
| optical isomer differentiation | one rotates plane polarised light clockwise (+), and one rotates it counterclockwise (-) |