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chem

organics

QuestionAnswer
-C=O | O-Na+ carboxylate salt (-anoate)
-C=O | O ester (-anoate)
-C=O | OH carboxylic acid (-noic acid)
-C=O | Cl acid chloride (-anoyl chloride)
-C=O | NH2 amide (-anamide)
-C=O ketone (-anone)
-C=O | H aldehyde (-anal)
alkene + Br2 or Cl2 haloalkane, addition
alkene + KMnO4 diol, addition
alkene + H2/Ni cataylst alkane, additon
alkene + H2SO4 (aq) or H+/H20 alcohol, addition
secondary alcohol + H+/Cr2O72+ or H+/MnO4- ketone, oxidation
primary alochol + H+/Cr2O72+ or H+/MnO4- carboxylic acid, oxidation
aldehyde + benedicts/tollens/fehlings solution or H+/Cr2O72+ or H+/MnO4- carboxylic acid, oxidation
alcohol + H2SO4 conc alkene, elimination
haloalkane + KOH (alc) or NaOH (alc) alkene, elimination
alcohol + SOCl2 or PCl5 or PCl3 haloalkane, substitution
haloalkane + NaOH (aq) or KOH (aq) alcohol, substitution
alkane + Br2 (aq) and UV light haloalkane, substitution
haloalkane + NH3 conc. amine, substitution
carboxylic acid + Na2CO3/NaHCO3 carboxylate salt, acid-base
anime + dilute HCl or H2SO4 ammonium salt, acid-base
alcohol + carboxylic acid with H2SO4 conc. cataylst ester ("# of carbons in alcohol"-yl "# of carbons in carboxylic acid"- noate, esterification
aldehyde + NaBH4 primary alcohol, reduction
ketone + NaBH4 secondary alcohol, reduction
ester + HCl, H2SO4 (or H+) alcohol + carboxylic acid, hydrolysis
ester + NaOH (aq) (or OH-) alcohol + CO-, hydrolysis
amide + NaOH (aq) (or OH-) COONa + NH3, hydrolysis
H+/Cr2O72- (with heat) observation orange to green
acid chloride + NH3 conc amide, substitution
acid chloride + H2O carboxylic acid, substitution
carboxylic acid + PCl5, SOCl2, PCl3 acid chloride, substitution
carboxylic acid + NH3 (aq) ammonium salt, acid-base
acid chloride + alcohol + no reagent ester, esterification
H+/MnO4- (with heat) observation purple to colourless
MnO4- observation purple to brown
Br2 water observation orange to colourless
benedict's and fehlings solution (with heat) observation blue to orange/brick red
tollens reagent (with heat) observation colourless to a silver mirror forming
UI with amine observation green to blue
UI with carboxylic acid observation green to red/orange
NaCO3 and NaHCO3 with acid observation bubbles of gas form
litmus paper and amine observation blue
litmus paper and carboxylic acid observation pink
amide pH neutral
6> carbon alcohol/carboxylic acid solubility insoluble
function groups that form two layers with water (insoluble) esters, hydrocarbons, and haloalkanes
water and acid chloride observation violent reaction with bubbles and steamy fumes, HCl gas is released which turns blue litmus red (indicating it's an acid)
benedict's/tollens + alcohol doesn't oxidise, they only oxidise aldehydes
polymer definition large molecule made up of repeating units called monomers
addition polymerisation the C=C in an alkene (unsaturated monomer) breaks and forms single bonds with adjacent monomers without losing atoms, producing only the polymer
condensation polymerisation two small molecules/monomers react to form a polymer, and one water molecule is lost/eliminated for each ester or amide linkage formed
amino acid definition monomers that have an amine group (-NH2), carboxylic acid group (-COOH), H, and variable R side chain all attached to the same carbon atom
peptide 2 or more amino acids joined together
dipeptide two amino acids joined together
polypeptide 3 or more amino acids joined together
protein natural polymer made up of long chains of amino acids joined together by peptide bonds
forming proteins when the -NH2 group of one amino acid reacts with the -COOH group of another, undergoing a condensation reaction to form a peptide bond, and eliminating one molecule of H2O
breaking proteins one H2O molecule is added per one peptide bond to break apart the amino acids, hydrolysis reaction
structural isomers same molecular formula, different structural formula
geometric isomers same molecular formula, different arragement in space
geometric isomer needs C=C, 2 different bonded groups on each C atom in the double bond
cis-isomers (geometric) groups of interest are on the same side of the C=C
trans-isomers (geometric) groups of interest are on opposite sides of the C=C
optical isomers same atoms and connectivity, but different 3D arrangement. they are non-superimposable mirror images of each other
optical isomer needs chiral carbon (C with four different groups bonded to it)
optical isomer differentiation one rotates plane polarised light clockwise (+), and one rotates it counterclockwise (-)
Created by: kaiashea
 

 



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