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Chemistry Regents 25

TermDefinition
physical property does not alter the chemical makeup
solid Particles are held in a rigid geometric pattern,definite shape and volume
liquid particles are not held in a rigid form, definite volume, but no definite shape
gas particles have minimal attractive forces, can expand/contract/move and fill any container, no definite volume or shape; spread indefinitely
element purest, simplest form of a substance that still has a unique set of properties; cannot be separated
compound a substance that contains two or more elements chemically combined in fixed proportions; has a formula
mixture A physical blend of two or more components; can be physically separated.
homogeneous mixture A mixture that is the same throughout; smooth; no chunks.
heterogeneous mixture A mixture that has different regions; chunky.
filtration separates based on particle size or solubility
chromatography separates a mixture based on polarity
separate by evaporation separates based on boiling point
distillation separate and capture liquids based on boiling points
period row on the periodic table
family or group column on the periodic table, elements have the same number of valence electrons
Noble Gases Group 18, don't react with any other elements (due to full valence shell)
diatomic elements exist only in pairs when alone HON-17
STP standard temperature and pressure
metals are solids at room temperature (except Hg), malleable, ductile, luster, good conductors of heat and electricity
nonmetals as solids they are brittle, dull, and poor conductors of heat and electricity
metalloids exhibit properties of metals and nonmetals
proton positive subatomic particle in the nucleus, atomic number
neutron neutral subatomic particle in the nucleus, contributes to the mass of the atom
electron negative subatomic particle in orbitals
ion an atom with more or less electrons than a neutral
octet rule atoms are most stable when they have a full valence shell
isotope atoms of the same element with the same number of protons but a different mass (different number of neutrons)
ground state all electrons are in their normal shells
excited state one or more electrons has "jumped" up to a higher shell
bright line spectrum pattern of light that each element produces when its electrons are excited and fall back to the ground state
Rutherford's gold foil experiment Alpha-particles were directed at a thin sheet of gold foil; most passed through the foil, but a few were deflected; this led to the discovery of the atomic nucleus.
wave mechanical model Current model of the atom where electrons are in clouds of probable location around the nucleus called orbitals
atomic radii the size of an atom
electronegativity the attraction of a nucleus for a new electron in a bond
ionization energy amount of energy needed to remove an electron
ionic bonding metal + nonmetal transfer electrons
polyatomic ions ions made with more than one atom
ionic properties high mp and bp, hard, conduct electricity as liquids or in aqueous solutions
covalent bond nonmetals share electrons
molecular formula shows how many atoms are in the molecule (only covalent compounds/molecules)
empirical formula shows the ratio of atoms (for covalent and ionic). This the reduced formula.
polar covalent bond nonmetals with different electronegativities share electrons unequally
nonpolar covalent bond nonmetals with the same (or close) electronegativities share electrons equally
single covalent bond one pair of electrons are shared (2 total)
double covalent bond two pairs of electrons are shared (4 total)
triple covalent bond three pairs of electrons are shared (6 total)
covalent properties low mp and bp, poor conductors
metallic bond a bond in a metal where the electrons move freely
hydrogen bonding the STRONG intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom (FON) is attracted to opposite charges of nearby molecules
dipole charged end of a polar molecule
molecule ion attraction attraction between an ion and water
reactants ingredients in a reaction (before)
products substances that are made (after)
reaction a chemical change that happens after time
law of conservation of mass matter cannot be created nor destroyed (equal mass on both sides of an equation)
synthesis reaction when two or more reactants combine to form a single product
decomposition reaction when a single compound is broken down
single displacement reaction when one atom replaces another in a reaction
double displacement reaction when two compounds switch "partners"
combustion reaction when a hydrocarbon combines with oxygen and forms carbon dioxide and water
mole measurement of number of atoms
temperature average kinetic energy
heat of fusion amount of energy needed to melt (or freeze) a solid
heat of vaporization amount of energy needed to boil (or condense) a substance
vapor pressure the pressure exerted by a vapor over a liquid
kinetic molecular theory particles in a gas are (1) moving in random straight line motion (2) are far apart compared to their size (3) are not attracted to each other
ideal gas a gas under low pressure and high temperature
pressure force exerted through particle collisions
Relationship between pressure and volume of a gas pressure and volume are inversely related at constant temperature
Relationship between volume and temperature of a gas volume and temperature are directly related at constant pressure
exothermic heat is given off
endothermic heat is added (required)
sublimation solid to gas
nucleus dense, central core of an atom, made up of protons and neutrons
orbital a region in which an electron of a particular amount of energy is most likely to be located
atomic mass the weighted average of the masses of the isotopes of an element
deposition gas to solid
allotropes a form of an element that is the same element in the same phase, but has different chemical and physical properties
ex. O₂ (oxygen) and O₃ (ozone)
polar molecule Polar bonds AND asymmetrical
nonpolar molecule has nonpolar bonds OR it has polar bonds and is symmetrical
dipole-dipole forces the positive end of one molecule attracts to the negative end of another
pure substance one thing; element or compound
ionic radius radius of the ion of an element, positive is smaller, negative is larger
Van Der Waal's forces weak attractions between nonpolar molecules
solute substance that is being dissolved
solvent substance that is doing the dissolving
aqueous solution solution where water is the solvent
solubility how easily or how much something dissolves
molarity concentration of a solution
electrolytes ionic substances that are dissolved in water; conduct electricity
saturated solution a solution that has dissolved as much as it possibly can
unsaturated solution a solution that can dissolved more of a solute
supersaturated solution a trick where a solution is heated to allow more solute to dissolve
What happens to the freezing point when more substance is dissolved in a solution? The freezing point decreases.
What happens to the boiling point when more substance is dissolved in a solution? The boiling point increases.
oxidation the loss of electrons (OIL)
reduction the gain of electrons (RIG)
oxidizing agent the chemical that is oxidizing something else (the one that's reduced)
reducing agent the chemical that is reducing something else (the one that's oxidized)
half reaction shows the oxidation half or the reduction half of the reactions (adding the two halved make the whole equation)
voltaic cell an electrochemical cell in which a spontaneous chemical reaction causes a flow of electrons
electrolytic cell cell that uses electrical energy to produce a chemical change that would otherwise not occur spontaneously
acids compounds that form hydrogen ions when dissolved in water
bases compounds that produce OH- in solution
Arrhenius theory the simplest definition of acids and bases
Arrhenius acid anything that ionizes in water and give off a hydrogen ion (H+) AKA hydronium ion (H3o+)
Arrhenius base anything that gives off an OH⁻
neutralization reaction acid + base → salt + water
titration a measured neutralization reaction (used to find an unknown) MV=MV
"Alternate" acid theory acids donate a proton (H⁺)
bases gain a proton (H+)
pH measure of how basic or acidic something is, low pH is acidic
radioactive isotopes called radioisotopes, all elements above atomic number 83 are radioactive and unstable (some below too)
transmutation when the nucleus of one atom transforms into the nucleus of a different atom
alpha decay when an unstable nucleus emits an alpha particle (weakest)
beta decay when an unstable nucleus emits a beta particle
positron decay when an unstable nucleus emits a positron
gamma radiation when an unstable nucleus emits a gamma ray (strongest)
artificial transmutation when an atom is hit by a particle (two things before the arrow)
natural transmutation when an atom decays without any other particles (one thing before the arrow)
half-life the amount of time it takes for half a nuclear substance to decay
fission a large atomic nucleus is split into two particles after a NEUTRON is shot at it, gives off energy (converted from mass)
fusion two small nuclei stick together to form a larger one (happens in the sun), gives off energy (converted from mass)
alcohols have an -OH group
aldehyde double bonded oxygen at the end of a carbon chain
ketone double bonded oxygen somewhere in the MIDDLE of the chain branching off a carbon
organic acid double bonded oxygen next to an -OH at the end of the chain
amine an NH₂ branch somewhere along the chain
amide an NH₂ and a double bonded oxygen on the end of a chain
substitution replacement of one or more hydrogen atoms in a saturated hydrocarbon with another group
addition adding one or more atoms at a double or triple bond
esterfication the process of making an ester from an organic acid and alcohol
saponification when an ester reacts with a base to make an alcohol and soap
fermentation when yeast breaks up sugar to make ethanol and carbon dioxide
polymerization forming one large chain from small pieces (addition of multiple monomers)
isomer compounds with the same molecular formula but a different structure
factors affecting rates of reaction: concentration increasing concentration increases the rate of a reaction
factors affecting rates of reaction: surface area Increasing surface area increases the rate of a reaction
factors affecting rates of reaction: pressure higher pressure = faster
factors affecting rates of reaction: catalysts presence of catalyst = faster
(creates an easier pathway for the reaction)
factors affecting rates of reaction: temperature higher temperature = faster
activation energy amount of energy needed for the reaction to happen
heat of reaction difference between the potential energy of the reactants and the products (ΔH)
equilibrium a reaction where the rates are equal and the concentrations are constant
phase equilibrium when the processes of freezing and melting or evaporating and condensing are occurring at equal rates
solution equilibrium the rate of dissolving and the rate of crystallization are equal
chemical equilibrium In a chemical reaction, the state in which the rate of the forward reaction equals the rate of the reverse reaction, so that the relative concentrations of the reactants and products do not change with time.
Le Châtelier's principle System shifts to counteract changes in equilibrium.
entropy the measure of randomness in a system
chemical property how a substance reacts with other chemicals
Created by: mharms
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