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ORGO
mechanisms
| Term | Definition |
|---|---|
| H2SO4 or TsOH or H3PO4 (acids) with secondary and tertiary alcohols | dehydration elimination through E1 |
| POCl3 and pyridine with secondary or tertiary alcohols | dehydration elimination through E2 |
| HX (HBr, HCl) with secondary or tertiary alcohols | substitution through SN1 |
| SOCl2 with secondary or teritirary alcohols | substitution through SN2 |
| PBr3 and pyridine with secondary or teritirary alcohols | substitution through SN2 |
| H2SO4 or TsOH or H3PO4 (acids) with primary alcohols | dehydration elimination through E2 |
| POCl3 and pyridine with primary alcohols | dehydration elimination through E2 |
| HX (HBr, HCl) with primary alcohols | substitution through SN2 |
| SOCl2 with primary alcohols | substitution through SN2 |
| PBr3 and pyridine with primary alcohols | substitution through SN2 |
| TsOH | elimination |
| H2SO4 | elimination |
| H3PO4 | elimination |
| POCl3 with pyridine | elimination |
| HX (HCl, HBr) | substitution |
| SOCl2 | substitution |
| PBr3 and pyridine | substitution |
| NaNH2 | elimination |
| SH with alkyl halides | SN2 |
| OTs | SN2 or E2 (bulky base) |
| BH3 with H2O2 and OH on an alkene | -addition of one OH -syn addition -OH on the least subsitutated carbon -produces enantiomers |
| H2SO4, H3PO4, TsOH (acids) with H20 on an alkene | -addition of one OH -syn and anti addition -produces two sets of enantiomers -OH on the most substituated carbon |
| Br2, Cl2 on an alkene | -addition of both alkyl halides -anti addition -produces enantiomers |
| Br2, Cl2 with H2O on an alkene | -addition of one alkyl halide and an OH -enantiomers |
| NaOH with water on an epoxide | adds two OH groups (diol) |
| HBr, HCl with an epoxide | adds alkyl halide and OH group |