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Thermo cht 3

TermDefinition
Simple Compressible Substance a substance whose magnetic effects and electrical effects are insignificant but changes in volume are very important For example water or a uniform mixture of non-reacting gases).
Simple Compressible System a system consisting of a simple compressible substance
State Principle The state of a simple compressible system at equilibrium can be uniquely determined by two independent intensive thermodynamic properties
Single-phase regions solid, liquid, vapor
Two-phase regions liquid-vapor (vaporization & liquefaction) solid-liquid (melting & freezing) solid-vapor (sublimation: gasification and solidification)
vaporization & liquefaction liquid-vapor
melting & freezing solid-liquid
sublimation: gasification and solidification solid-vapor
Triple line the line along which three phases can exist in equilibrium
Critical point the point for the maximum temperature and pressure at which liquid and vapor phases can coexist in equilibrium.
Triple point a point of the triple line projected onto the phase diagram
isotherms constant-temperature lines drawn in p -v diagram
isobars Note the constant-pressure lines
Saturation temperature the temperature at which a phase change takes place at a fixed pressure
Saturation pressure the pressure at which a phase change takes place at a fixed temperature
Subcooled liquid (compressed liquid) the liquid of which temperature is lower than the saturation temperature
Saturated liquid a substance that exists as liquid at the saturation condition
Quality (x) the ratio of the mass of vapor present to the total mass of the liquid-vapor mixture - an intensive property
Saturated vapor a substance that exists as vapor at the saturation condition
dry saturated vapor quality is 1.
Superheated vapor a vapor of which temperature is higher than the saturation temperature
supercritical fluid If the pressure is equal to or higher than pc
Specific Heats → intensive properties; also called heat capacities)
thermally perfect When u and h of a gas are functions of temperature only
calorically perfect when Cv and Cp are constant monatomic gases or other gases with small temperature change
isobaric process p = constant
isometric process Volume is constant
Created by: thermosucks
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