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Kinetic Molecular
Kinetic Molecular Theory
Term | Definition |
---|---|
Kinetic-Molecular Theory | Theory based on the idea that particles of matter are always in motion. |
First Assumption | Gases consist of large numbers of tiny particles that are far apart relative to their size. The volume of gas particles are considered to be negligible (or zero). |
Second Assumption | Collisions (between gas particles and container walls and , between particles) are elastic collisions (kinetic energy (or KE) is conserved). Pressure exerted by gases is caused by collisions of the gas molecules within the walls of the container. |
Third Assumption | Gas particles are in continuous, rapid, random motion and possess KE. |
Fourth Assumption | There are no forces of attraction or repulsion between gas particles. |
Fifth Assumption | The average KE of gas particles depends on the temp. of the gas; KE=1/2mv^2 a. Mass is a constant. b. KE is dependent upon velocity (v) or speed (speed increases with an increase in temp.). c. Gases at the same temp. have the same average KE. |
Kinetic Energy | The energy of motion. |
Ideal Gas | A hypothetical gas that perfectly fits all the assumptions of the kinetic-molecular theory. |
Elastic Collision | Collision in which there is no net loss of total kinetic energy. |
Diffusion (Assumption 3) | Spontaneous mixing of the particles of two substances caused by their random motion. |
Effusion (Assumption 3) | A process by which gas particles pass through a tiny opening. |
Real Gas | A gas that does not behave completely according to the assumptions of the kinetic-molecular theory. |
Expansion (Assumption 3 & 4) | Gases spontaneously fill the container they occupy. |
Fluidity (Assumption 4) | Gas particles glide past one another. |
Low Density (Assumption 1) | The gaseous state is 1/1000 the density of the liquid state. |
Compressibility (Assumption 1) | The volume of a gas can be decreased. |
How Real Gases differentiate from Ideal Gases | 1. High Pressure: the vol. of particles can no longer be considered zero. 2. Low Temp.: KE is no longer high enough to overcome attractive forces. 3. Polar Gases: The more polar the gas is, the greater the attractive force (because of partial charges). |