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Chapter 13 Chemistry
Question | Answer |
---|---|
The Four Colligative Properties | vapor pressure, boiling point, freezing point, osmosis |
The # Of Vapor Particles In A Pure Solvent Is... | 8 |
The # Of Vapor Particles In A Solution With A Non-Volatile Solute Is... | 6 |
The # Of Vapor Particles In A Solution With A Volatile Solute Is... | 5 |
In A Non-Volatile Solution, The Vapor Phase Consists Of... | only solvent |
In A Volatile Solution, The Vapor Phase Consists Of... | solvent & solute |
In A Solution, There Are Less Solvent Particles In The Vapor Phase Because... | the # of surface particles decreases, reducing the # available to evaporate |
Non-Volatile Solute Equation | Psoln = (Psolv)(Xsolv) |
Mole Fraction Equation | X = mole component / moles total |
Volatile Solute Equation | Psoln = (Pcomp1)(Xcomp1) + (Pcomp2)(Xcomp2) + ... |
Mole Fraction Of Vapor Component Equation | Xcomp1 vapor = Pcomp1 vapor / Psoln |
How & Why The BP Changes When A Solute Is Added | decreases the vapor pressure of the solution, so it takes more KE to boil (VPsoln=Patm) |
The Atmospheric Pressure Is Equal To... | the vapor pressure of a solution |
Occurrences During Freezing | the substance will form an orderly arrangement & H-Bonds form |
How & Why The FP Changes When A Solute Is Added | solute makes the IMFA attraction more difficult to form, so it takes a lower temperature to freeze |
BP Equation | Δt=mki (k is the BP constant of the solvent) |
FP Equation | Δt=mki (k is the FP constant of the solvent) |
In BP & FP Equations, 'k' is... | the BP or FP constant solvent |
In BP & FP Equations, 'Δt' is... | the change in BP or FP |
In BP & FP Equations, 'm' is... | molality (moles solute/kg solvent) |
In BP & FP Equations, 'i' is... | Van't Hoff Factor = dissociation factor = # solute particles in soln |
Ionization For Non-Ionizing Solutes | 1 organic/molecular - non-metals |
Ionization For Ionizing Solutes | i = # of ions in solution - soluble ionic salts |
Ion Pairing | for a brief moment, ions pair & reduce the # of free ions in a solution |
To Calculate The Ionization Factor Of Pairing Ions... | multiply the oxidation numbers and take the absolute value ((ex: NaCl -> ∣(1)(-1)∣= 1)) |
The Higher The Product Of The Oxidation Numbers... | the higher the ion pairing, higher the attraction, higher the charges |
How Ion Pairing Affects BP/FP | ion pairing will decrease 'i' value & Δt will be smaller |
Steps To Calculate Molar Mass Of An Unknown Solute | 1) calculate Δt or change in BP/FP -- 2) find k solvent & i solute -- 3) plug & solve -- 4) DA from grams to moles -- 5) g/mol |
Steps To Calculate Grams Of Solute Needed | 1) calculate Δt or change in BP/FP -- 2) find k solvent & i solute -- 3) plug & solve -- 4) DA from grams to moles -- 5) g solute |
Osmotic Pressure | the external pressure that needs to be exerted to stop osmosis |
Osmosis | "the spontaneous net movement or diffusion of solvent molecules through a selectively-permeable membrane" |
Semi-Permeable | the solvent molecules can cross, but solute cannot |
The NET Movement Of A Solvent Is... | towards the higher solute concentration |
\The NET Movement Of A Solvent Stops When... | it does not stop |
Equilibrium Of NET Movement | # leaving = # entering |
When Equilibrium Is Reached, The Solvent Side Of The Tube Will Be... | higher |
Osmotic Pressure Equation | P=n/v x RT (P & capital π equal MRT) |