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Chapter 13 Chemistry

QuestionAnswer
The Four Colligative Properties vapor pressure, boiling point, freezing point, osmosis
The # Of Vapor Particles In A Pure Solvent Is... 8
The # Of Vapor Particles In A Solution With A Non-Volatile Solute Is... 6
The # Of Vapor Particles In A Solution With A Volatile Solute Is... 5
In A Non-Volatile Solution, The Vapor Phase Consists Of... only solvent
In A Volatile Solution, The Vapor Phase Consists Of... solvent & solute
In A Solution, There Are Less Solvent Particles In The Vapor Phase Because... the # of surface particles decreases, reducing the # available to evaporate
Non-Volatile Solute Equation Psoln = (Psolv)(Xsolv)
Mole Fraction Equation X = mole component / moles total
Volatile Solute Equation Psoln = (Pcomp1)(Xcomp1) + (Pcomp2)(Xcomp2) + ...
Mole Fraction Of Vapor Component Equation Xcomp1 vapor = Pcomp1 vapor / Psoln
How & Why The BP Changes When A Solute Is Added decreases the vapor pressure of the solution, so it takes more KE to boil (VPsoln=Patm)
The Atmospheric Pressure Is Equal To... the vapor pressure of a solution
Occurrences During Freezing the substance will form an orderly arrangement & H-Bonds form
How & Why The FP Changes When A Solute Is Added solute makes the IMFA attraction more difficult to form, so it takes a lower temperature to freeze
BP Equation Δt=mki (k is the BP constant of the solvent)
FP Equation Δt=mki (k is the FP constant of the solvent)
In BP & FP Equations, 'k' is... the BP or FP constant solvent
In BP & FP Equations, 'Δt' is... the change in BP or FP
In BP & FP Equations, 'm' is... molality (moles solute/kg solvent)
In BP & FP Equations, 'i' is... Van't Hoff Factor = dissociation factor = # solute particles in soln
Ionization For Non-Ionizing Solutes 1 organic/molecular - non-metals
Ionization For Ionizing Solutes i = # of ions in solution - soluble ionic salts
Ion Pairing for a brief moment, ions pair & reduce the # of free ions in a solution
To Calculate The Ionization Factor Of Pairing Ions... multiply the oxidation numbers and take the absolute value ((ex: NaCl -> ∣(1)(-1)∣= 1))
The Higher The Product Of The Oxidation Numbers... the higher the ion pairing, higher the attraction, higher the charges
How Ion Pairing Affects BP/FP ion pairing will decrease 'i' value & Δt will be smaller
Steps To Calculate Molar Mass Of An Unknown Solute 1) calculate Δt or change in BP/FP -- 2) find k solvent & i solute -- 3) plug & solve -- 4) DA from grams to moles -- 5) g/mol
Steps To Calculate Grams Of Solute Needed 1) calculate Δt or change in BP/FP -- 2) find k solvent & i solute -- 3) plug & solve -- 4) DA from grams to moles -- 5) g solute
Osmotic Pressure the external pressure that needs to be exerted to stop osmosis
Osmosis "the spontaneous net movement or diffusion of solvent molecules through a selectively-permeable membrane"
Semi-Permeable the solvent molecules can cross, but solute cannot
The NET Movement Of A Solvent Is... towards the higher solute concentration
\The NET Movement Of A Solvent Stops When... it does not stop
Equilibrium Of NET Movement # leaving = # entering
When Equilibrium Is Reached, The Solvent Side Of The Tube Will Be... higher
Osmotic Pressure Equation P=n/v x RT (P & capital π equal MRT)
Created by: abievans
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