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Organic Chemistry
Intro to Organic Chemistry
| Question | Answer |
|---|---|
| this is the study of carbon containing compounds and their properties | Organic Chemistry |
| means “derived from living organisms.” | Organic |
| the belief that natural products needed a “vital force” to create them | "vitalism" |
| was the study of gases, rocks, and minerals, and the compounds that could be made from them. | Inorganic Chemistry |
| “Father of Organic Chemistry”, converted ammonium cyanate, made from ammonia and cyanic acid, to urea simply by heating it in the absence of oxygen | Friedrich Wöhler |
| Bark of Cinchona trees – chewed for years to treat symptoms of malaria | Quinine |
| Ancient Egyptians ate roasted ox liver in the belief that it improved night vision | Vitamin A |
| An ancient antipyretic involved chewing willow bark | Salicin a derivative of salicylic acid |
| Mid 17th century a new compound was synthesized called acetylsalicylic acid | Aspirin |
| Fermentation of grains and fruits | Ethanol |
| In ancient Bengal, Java and Guatemala, plants provided a deep blue substance used to color clothing | Indigo |
| Ancient Phoenicians used an extract from a snail to color cloth | Tyrian purple |
| Plant known as Belladona has been used for centuries as a poison | Atropine (found in the stems of tomato plants |
| He isolated acidic components from grapes and lemons by forming precipitates with Ca++ or Pb then adding mineral acids | Carl William Scheele |
| isolated acidic components from grapes and lemons by forming precipitates with Ca++ or Pb then adding mineral acids to form | Tartaric acid or citric acid |
| Also isolated Uric acid from urine | Carl William Scheele |
| He isolated a compound from opium extracts | FRIEDRICH SERTURNER |
| a compound from opium extracts | morphine |
| He isolated a crystalline material from animal tissues | MICHEL CHEVREUL |
| a compound from animal tissues | cholesterol |
| They isolated an alkaloid STRYCHNINE | PIERRE PELLETIER & JOSEPH CAVENTOU |
| perfected the science of organic analysis based on Lavoisier’s early work | JUSTUS LEIBIG |
| described the substances obtained from living organisms as organic compounds & that they were composed of only C &H | JONS J. von BERZELIUS |
| described what was known as the VITAL FORCE THEORY | BERZELIUS & Charles GERHARDT |
| showed that all classes of organic compounds could be synthesized | MARCELLIN BERTHELOT |
| He prepared ethane via electrolysis of potassium acetate | HERMANN KOLBE |
| He prepared butane from iodoethane & zinc | SIR EDWARD FRANKLAND |
| He discovered amines; synthesis of higher alkanes from 2 alkyl halides (coupling reaction | CHARLES WURTZ |
| He showed how ethers could be prepared from K salt of an alcohol and alkyl iodide | ALEXANDER WILLIAMSON |
| He prepared the first commercially synthetic dye mauve | WILLIAM PERKIN |
| He introduced the term “chemical structure | BUTLEROV |
| He introduced the idea of closed valence bonds… but the concept was still vague on how the atoms in carbon were attached | AUGUST KEKULE |
| He introduced the concept of bond formation due to sharing of electrons… covalent bond | Gilbert Lewis |
| He theorized the concept of acids and bases according to the electron shared or accepted | Gilbert Lewis |
| He introduced the orbital concept of molecules | HEISENBERG & SHRODINGER |
| He synthesized protoporphyrin | HANS FISCHER |
| isolated from ants and named after the Latin word for ant, formica; | Formic acid |
| - Isolated from urine | Urea |
| A painkiller named after the Greek god of dreams, Morpheus; | Morphine |
| Adolf von Baeyer named this compound in honor of a woman named Barbara | Barbituric acid |
| n 1892, a group of 34 European chemists met in Switzerland and developed a system of organic nomenclature called the | Geneva rules. |
| 34 European chemists met in Switzerland | International Union of Pure and Applied Chemistry, or IUPAC (pronounced “I–YOU–PACK”). |
| Names produced by IUPAC rules are called | systematic names. |